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Specific Process Knowledge/Lithography/Development

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The content on this page, including all images and pictures, was created by DTU Nanolab staff, unless otherwise stated.

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Development Comparison Table

Manual beaker development Developer: SU8 (Wet bench) Developer: E-beam 02 Developer: TMAH Manual 02 Developer: TMAH UV-lithography Developer: TMAH Stepper
Purpose

Fall-back option if you have a process, which is not compatible with the automatic, or semi-automatic, tools

Requires individual risk assessment for TMAH development!

Development of:

  • SU-8

Development of:

  • ZEP 520A
  • AR-P 6200.xx (CSAR)

Development of:

  • AZ nLOF
  • AZ MiR 701
  • AZ 5214E
  • AZ 4562
  • DUV resists

Development of:

  • AZ nLOF
  • AZ MiR 701
  • AZ 5214E
  • AZ 4562
  • DUV resists

Post-exposure baking

Development of:

  • DUV resists

Post-exposure baking

Developer Process dependent mr-Dev 600 (PGMEA)
  • ZED N-50
  • AR 600-50
AZ 726 MIF (2.38% TMAH in water) AZ 726 MIF (2.38% TMAH in water) AZ 726 MIF (2.38% TMAH in water)
Method Submersion Submersion Puddle Puddle Puddle Puddle
Handling

Manual handling in beakers

  • Chip bucket
  • Single wafer carrier
  • Carrier for up to 5 wafers
  • Chip bucket
  • Single wafer carrier
  • Carrier for up to 6 wafers
  • Vacuum-free edge-grip chucks for 50 mm, 100 mm & 150 mm, and 200 mm substrates
  • Chip chuck for chips & 50 mm substrates
  • Vacuum-free edge-grip chuck for 100 mm & 150 mm substrates
  • Chip chuck for chips & 50 mm substrates
Vacuum chuck Vacuum chuck
Process temperature Room temperature Room temperature Room temperature Room temperature Room temperature Room temperature
Process agitation No agitation allowed Magnetic stirrer Rotation Rotation Rotation Rotation
Process rinse Process dependent IPA IPA DI water DI water DI water
Substrate size
  • Chips
  • 50 mm wafers
  • 100 mm wafers
  • 150 mm wafers
  • Chips
  • 50 mm wafers
  • 100 mm wafers
  • 150 mm wafers
  • 200 mm wafers
  • Chips (5mm to 2")
  • 50 mm wafers
  • 100 mm wafers
  • 150 mm wafers
  • 200 mm wafers
  • Chips (5mm to 50 mm)
  • 100 mm wafers
  • 150 mm wafers
  • 100 mm wafers
  • 150 mm wafers
  • 200 mm wafers (may require tool change)
  • 100 mm wafers
  • 150 mm wafers
  • 200 mm wafers (may require tool change)
Allowed materials All cleanroom approved materials
  • Silicon and glass substrates
  • Film or pattern of all but Type IV
All cleanroom approved materials
  • All cleanroom approved materials
  • Film or pattern of all types
  • Silicon and glass substrates
  • Films, or patterned films, of any material except type IV (Pb, Te)
  • Silicon, III-V, and glass substrates
  • Films, or patterned films, of any material except type IV (Pb, Te)
Batch size 1 - 5 1 - 6 1 1 1 - 25 1 - 25


Developer-1 and Developer-2

Developer-1 (right) and Developer-2 (left) are located in C-1

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This equipment was decommissioned January 2017!

Developer-1 and Developer-2 are manual developer baths for submersion development of AZ 5214E and AZ 4562 resists in AZ 351B developer. The developer is mixed 1:5 in water by the user prior to development start, and the wafer cassette is agitated manually by the user during development. The development time is controlled manually by the user. After development, the substrates are rinsed with water in the bench.

The user APV, and contact information can be found in LabManager: Developer-1 Developer-2

Process information

Standard development time using vigorous agitation:

AZ 5214E:

  • 1.5µm resist: 60 sec
  • 2.2µm resist: 70 sec
  • 4.2µm resist: 3 min

AZ 4562:

  • 10µm resist: 5 min

Standard development procedure:

  • Before using one of developer baths, please check the "Litho4_Dev-7up-KOH" logbook to find out when they were last used. A fresh bath can be reused without problems.
  • The main rule is a developer made yesterday must be changed.
  • During development, agitate the substrates by moving the carrier up and down.
  • Rinse substrates with water for 4-5 min. after development.
  • Spin-dry substrates or dry with nitrogen gun after rinsing.

Procedure for making a new developer

1. Switch off the heater, and dump the old developer.

2. 800ml "Developer AZ 351B" is mixed with 4000ml water in a special container in the fume hood.

3. Fill the bath with the developer mixture, and heat it to 22°C before use.

Equipment performance and process related parameters

Purpose

Development of

  • AZ 5214E
  • AZ 4562
Developer

AZ 351B diluted 1:5 in water

(NaOH and sodium borate salt)

Method Development

Submersion

Handling

Cassette

Process parameters Temperature

22°C

Agitation

Manual

Rinse

DI water

Substrates Substrate size
  • 100 mm wafers
Allowed materials

Silicon, glass, and polymer substrates

Film or pattern of all types

Batch

1-8


Developer-6inch

The Developer: 6inch bench is located in E-4

Feedback to this section: click here

This equipment will be decommissioned December 2019!

The Developer: 6inch bench is an automated developer bath for submersion development of AZ 5214E and AZ 4562 resists in AZ 351B developer. The developer is mixed 1:5 in water by the equipment prior to development start. The developer is circulated during development, and the wafer cassette may be agitated by a mechanical elevator. The development time is controlled manually by the user. After development, the substrates are rinsed with water in the bench.

The user manual, user APV, and contact information can be found in LabManager

Process information

Standard development time:

AZ 5214E:

  • 1.5µm resist: 60 sec
  • 2.2µm resist: 70 sec
  • 4.2µm resist: 3 min

AZ 4562:

  • 10µm resist: 5 min

Equipment performance and process related parameters

Purpose

Development of

  • AZ 5214E
  • AZ 4562
Developer

AZ 351B diluted 1:5 in water

(NaOH and sodium borate salt)

Method Development

Submersion

Handling

Cassette

Process parameters Temperature

22°C

Agitation

Circulation and mechanical

Rinse

DI water

Substrates Substrate size
  • 100 mm wafers
  • 150 mm wafers
Allowed materials

Silicon, glass, and polymer substrates

Film or pattern of all types

Batch

1-25


The content on this page, including all images and pictures, was created by DTU Nanolab staff, unless otherwise stated.

Manual beaker development in fumehood

Beaker development, in fume hood 09: UV development or fume hood 10: e-beam development, is a fall-back option if you have a process, which is not compatible with the automatic, or semi-automatic, tools. We always recommend using, or at least trying, the automatic and semi-automatic tools, instead of using manual beaker development.

Manual beaker development is necessary for some processes, but should be avoided if possible, due to the fact that it is notoriously difficult to get a stable repeatable process - especially when multiple users are sharing the same process; everybody simply does things a bit different from each other, which leads to changes in the process outcome. Some processes have a very narrow process window, which makes them inherently sensitive to small changes in the development. The manual development also has a much greater chance of producing particles, both from the operator and the environment.

Finally the safety of the operator is at a significantly higher risk, since any manual handling of chemicals carries the risk of accidental spills with it. This is especially problematic if the developer is TMAH based, where direct skin exposure of >1% TMAH on a few percent of the body must be treated as a life-threatening event.

Special rules for manual beaker development of TMAH

  • Automatic agitation methods are not allowed - this includes magnetic stirring or sonication
  • Manual agitation methods, which create large waves or turbulence in the development solution, are not allowed
  • Users must submit a risk assessment for any process requiring manual beaker development of TMAH based developers
  • Users requiring manual beaker development of TMAH based developers must additionally provide valid reasons for not using the already available automatic and semi-automatic tools

Standard manual beaker development procedure

 
Standard procedure for manual beaker development in fume hood:
1) Submerge exposed substrate into development solution
2) When timer ends, move substrate directly into Rinse 1
3) After a few seconds, move substrate into Rinse 2*
4) Remove developed substrate for drying
(*It is allowed to omit the Rinse 2 step)

The standard procedure for manual beaker development in a fume hood is as follows:

  1. Prepare development process
  2. Perform development
  3. Clean up

Prepare development process

  • Write the chemical label, which must always be present in your chemical setup - your write your label before pouring the chemical
  • Find the beakers required for your process
  • Find the items required for holding/submerging your substrate during the process
  • Find carriers or other storage units for placing your substrate after the process has finished
  • Find a timer - make sure it works as you expect it to, before submerging your substrate into the development solution and discovering that the timer is in fact broken
  • Get some cleanroom wipes and keep them nearby, for wiping any drops spilled during handling
  • Do not cover too many of the exhaust holes in the fume hood table, as this will reduce the efficiency of the exhaust, which reduces safety
  • Do not place your beakers too close to the fume hood sash, as this can make it difficult to efficiently extract the fumes escaping from the beakers, which reduces safety

Perform development

  1. Put on the appropriate personal protection gear
  2. Pour rinsing agent into Rinse 1 and Rinse 2 beakers - typically DI water or IPA
  3. Pour development solution into development beaker
  4. Place exposed substrate in the appropriate carrier
  5. Set timer
  6. Submerge substrate into development beaker
  7. Start timer immediately
  8. When timer is 5 seconds from ending, prepare to lift the substrate out of the development beaker
  9. Lift substrate out of development beaker - it can help to lift it at a slight angle, to allow liquids to drain more easily from large surfaces
  10. Submerge it immediately into Rinse 1
  11. Agitate up/down for at least a few seconds
  12. Move substrate into Rinse 2*
  13. Agitate slightly
  14. The developed substrate can now be removed and dried

(*It is allowed to omit the Rinse 2 step)

Clean up

  • Pour Rinse 1 and Rinse 2 into appropriate waste: water goes into the sink, IPA goes into C-waste drain
  • Rinse beakers with the DI-water gun
  • Pour development solution into appropriate waste: solvent based developer goes into C-waste drain. NB! TMAH is an aqueous alkaline solution, which must never be mixed with solvents! TMAH waste goes into the dedicated TMAH waste container, stored in the chemical cabinet in E-4.
  • If your developer solution is not TMAH based:
    • Rinse beaker 3 times, discard water into sink
  • If your developer solution is TMAH based:
    • Rinse beaker once with DI-water and discard this into the TMAH waste
    • Rinse beaker two more times, discarding the water into the sink
  • Hang all beakers to dry on the drying rack
  • Erase the chemical label text
  • Wipe any droplets on the fume hood surface
  • Discard any napkins/other trash in the bin inside the fume hood


The content on this page, including all images and pictures, was created by DTU Nanolab staff, unless otherwise stated.

Developer: SU8 (Wet Bench)

 
The Developer: SU8 (Wet Bench) is located in E-4.

Tool description
The Developer: SU-8 (wet bench) is a manually operated wet bench for submersion development of SU-8 photoresist in PGMEA (supplied in the cleanroom as the product mr-Dev 600).

The SU-8 development is a three-stage process:

  1. Submerge into "FIRST" bath to dissolve the bulk of the resist
  2. Submerge into "FINAL" bath to finish the development
  3. Submerge into "RINSE" bath to stop the development process and rinse the substrates

The development time is controlled manually by the user. After development the substrates are dried in the empty bath, which is dedicated for drying.

Product: Arias wet bench
Year of purchase: 2023
Location: Cleanroom E-4

User manual
The user manual and contact information can be found in LabManager - requires login

Tool training
Training on the tool requires users to complete the lithography TPT followed by online tool training and hands-on authorization training.

Equipment performance and process related parameters

Tool purpose

Development of:

  • SU-8
Developer mr-Dev 600 (PGMEA)
Development method Submersion
Handling method Multi- or single wafer holder
Process temperature Room temperature
Process agitaion Magnetic stirrer
Process rinse IPA
Substrate sizes
  • Chips
  • 50 mm wafers
  • 100 mm wafers
  • 150 mm wafers, check the liquid level in the baths
  • 200 mm wafer, check the liquid level in the baths
Substrate materials
  • Silicon and glass substrates
  • Film, or pattern, of all materials except Type IV
Substrate batch size 1-6


Process information

Several aspects of the SU-8 processing outcome are affected by the development process:

  • The lithographic resolution is affected by the time between PEB (post-exposure bake) and development, as the cross-linking process continues in the interface between exposed and unexposed regions even at room temperature
  • Cracks in the structures is affected by two things; the development time, and how much has previously been developed in the developer bath. Cracking is worse with longer development time, and worse in a fresh developer bath. This effect of the developer quickly saturates after developing 5-10 wafers
  • The stability of fine structures (high aspect ratio structures) is affected by the rinse after development, as the lower surface tension of IPA compared to PGMEA reduces pattern collapse during drying


Development time
Development time is strongly dependent on the SU-8 thickness:

  • Minimum development time: 1 min per 20 µm in FIRST bath
  • Maximum development time: SU-8 is not very sensitive to over-development


Recommendations for development time:

  • ≤5 µm: 2 minutes in FIRST bath, followed by 2 minutes in FINAL bath
  • ~40 µm: 5 minutes in FIRST bath, followed by 5 minutes in FINAL bath
  • ≥180 µm: 15 minutes in FIRST bath, followed by 15 minutes in FINAL bath

The content on this page, including all images and pictures, was created by DTU Nanolab staff, unless otherwise stated.

Developer: E-beam 02

 
Developer: E-beam 02 is located in E-4.

Tool description
The Developer: E-beam 02 is a semi-automatic and programmable single substrate developer system, which can be used for development of resists on chips, 50 mm, 100 mm, 150 mm and 200 mm substrates. The development is done using ZED-N50 or AR 600-50 developers and IPA for rinsing.

Single substrates are loaded manually into the tool, but the developer dispense, puddle time, agitation, rinse and drying is controlled by the tool.

Product: Laurell EDC-650Hz-8NPPB-IND
Year of purchase: 2024
Location: Cleanroom E-4

User manual
The user manual and contact information can be found in LabManager - requires login

Tool training
Training on the tool requires users to complete the lithography TPT followed by the online tool training and a hands-on authorization training.
The tool training video is part of the online tool training, but can also be viewed here (the video is for Developer: TMAH Manual 02, but the two tools are almost identical).

Equipment performance and process related parameters

Tool purpose

Development of:

  • AR-P 6200.xx (CSAR)
  • ZEP 520
  • Other E-beam resists
Developer
  • AR 600-50
  • ZED N-50
Development method Puddle
Handling method
  • Non-vacuum chuck for 200 mm wafers
  • Non-vacuum chuck for 100 mm & 150 mm wafers
  • Non-vacuum chuck for 50 mm wafers
  • Non-vacuum chuck for chips
Process temperature Room temperature
Process agitaion 4 cycles per minute
Process rinse IPA
Substrate sizes
  • Chips
  • 50 mm wafers
  • 100 mm wafers
  • 150 mm wafers
  • 200 mm wafers
Substrate materials
  • All cleanroom allowed materials
  • Film, or pattern, of all materials except Type IV
Substrate batch size 1


Process information

All recipes use the following structure:

  1. Pressurize the developer canister
  2. Dispense puddle while rotating substrate slowly
  3. Puddle development with/without agitation of substrate
  4. Spin off developer
  5. Clean substrate with IPA
  6. Dry substrate and chamber with nitrogen


Multi puddle
Multi puddle recipes repeat steps 2-4 for the given number of puddles.

Process recipes

(Updated 2026-01-14, JEHEM)

N50 recipes have the letter "N" in them. AR-600-50 recipes have the letter "A" in them. The number is the development time in seconds:

  • 01 Rinse
  • 02 N 15
  • 03 N 30
  • 04 N 60
  • 05 N 90
  • 06 N 120
  • 07 N 180
  • 08 N 300
  • 09 N 600
  • 10 N 2x60
  • 11 N 5x60
  • 12 A 15
  • 13 A 30
  • 14 A 60
  • 15 A 90
  • 16 A 120
  • 17 A 180
  • 18 A 300
  • 19 A 600
  • 20 A 2x60
  • 21 A 5x60
  • 30 N 3x60s
  • NILT AR
  • NILT MOE
  • NILT p30
  • NILT p31
  • NILT p32

Agitation

4 cycles per minute, 30 rpm, 30 rpm/s.

The content on this page, including all images and pictures, was created by DTU Nanolab staff, unless otherwise stated.

Developer: TMAH Manual 02

 
Developer: TMAH Manual 02 is located in E-4.

Tool description
The Developer: TMAH manual 02 is a semi-automatic and programmable single substrate developer system, which can be used for development of resists on chips, 50 mm, 100 mm and 150 mm substrates. The development is done using AZ 726 MIF, which is a 2.38% TMAH solution with wetting agent.

Single substrates are loaded manually into the tool, but the developer dispense, puddle time, agitation, rinse and drying is controlled by the tool.

Product Laurell EDC-650-HZB-23NP
Year of purchase 2016
Tool modification

Converted from e-beam solvent developer to UV TMAH developer in 2024
Added media flow controllers for developer, rinse and drying media in 2025

Location Cleanroom E-4

User manual
The user manual and contact information can be found in LabManager - requires login

Tool training
Training on the tool requires users to complete the lithography TPT followed by the online tool training and a hands-on authorization training.
The tool training video is part of the online tool training, but can also be viewed here.

Equipment performance and process related parameters

Tool purpose

Development of UV resists:

  • AZ nLOF 2020
  • AZ MIR 701
  • AZ 5214E
  • AZ 4562

Development of DUV resists:

  • KrF M230Y
  • KrF M35G
Developer AZ 726 MIF (2.38% TMAH)
Development method Puddle
Handling method
  • Non-vacuum chuck for 100 mm & 150 mm wafers
  • Non-vacuum chuck for chips and 50 mm wafers
Process temperature Room temperature
Process agitaion 15 cycles per minute
Process rinse DI water
Substrate sizes
  • Chips
  • 50 mm wafers
  • 100 mm wafers
  • 150 mm wafers
Substrate materials
  • All cleanroom allowed materials
  • Film, or pattern, of all materials except Type IV
Substrate batch size 1
Media flow rates
  • AZ 726 MIF (TMAH): 300 ml/min
  • Process DI water: 400 ml/min
  • Backside rinse DI water: 140 ml/min
  • Process Nitrogen: 20 l/min


Process information

All recipes use the following structure:

  1. Pressurize the TMAH canister
  2. Pre-wet substrate at high RPM
  3. Dispense puddle while rotating substrate slowly
  4. Puddle development with agitation of substrate
  5. Spin off developer
  6. Clean substrate and chamber with DI water
  7. Dry substrate and chamber with nitrogen


Multi puddle
Multi puddle recipes repeat steps 2-4 for the given number of puddles.

Process recipes

(Updated 2026-01-12, JEHEM)

  • -Rinse-
  • 1x015s
  • 1x030s
  • 1x060s
  • 1x120s
  • 2x060s
  • 5x060s

Agitation

Testing showed that adding agitation to the puddle step gave better uniformity in the development rate over the entire area of the substrate as well as increased development rate.

Tests were performed on under-exposed resist, specifically for showing the difference between the agitation and non-agitation puddle development - the measured results cannot necessarily be transferred directly to a working process, only the vague general behavior of the two process setups; faster/slower development speed and better/worse uniformity across substrate.

 
Development rate for under-exposed resist test
 
Non-uniformity for under-exposed resist test
Non-agitation Agitation
Test results
  • Slower development
  • Worse uniformity
  • Faster development
  • Better uniformity
Normalized development rate 1 1.20
Non-uniformity 21% 11%
Agitation None 15 cycles per minute, 20 rpm, 500 rpm/s
Substrate 100 mm SSP silicon
Resist film 1.5 µm AZ 5214E
Exposure dose 50 mJ/cm2 (~50% of normal dose)
Development Single puddle for 60 seconds
Developer AZ 726 MIF (2.38% TMAH)


The content on this page, including all images and pictures, was created by DTU Nanolab staff, unless otherwise stated.

Developer: TMAH UV-lithography

 
Developer: TMAH UV-lithography is located in E-4.

Tool description
The Developer TMAH UV-lithography is a fully automatic and programmable cassette-to-cassette system, which can be used for post-exposure baking and development of UV resists on 100 mm and 150 mm substrates. The development is done using AZ 726 MIF, which is a 2.38% TMAH solution with wetting agent.

The developer dispense, puddle time, agitation, rinse and drying is controlled by the tool.

Product: Süss MicroTec Gamma 2M developer
Year of purchase: 2014
Location: Cleanroom E-4

Chuck size and lift pins
Link to information about developer chuck size and hotplate pin positions.

User manual
The user manual and contact information can be found in LabManager - requires login

Tool training
Training on the tool requires users to complete the lithography TPT followed by the online tool training and a hands-on authorization training.
The tool training video is part of the online tool training, but can also be viewed here.

Equipment performance and process related parameters

Tool purpose

Development of:

  • AZ nLOF 2020
  • AZ MIR 701
  • AZ 5214E
  • AZ 4562

Development of DUV resists:

  • KrF M230Y
  • KrF M35G
Developer AZ 726 MIF (2.38% TMAH)
Development method Puddle
Handling method
  • Vacuum chuck for 100 mm & 150 mm wafers
Process temperature Room temperature
Process agitation 1 cycles per 30 seconds
Process rinse DI water
Substrate sizes
  • 100 mm wafers
  • 150 mm wafers
Substrate materials
  • Silicon or glass substrates
  • Film, or pattern, of all materials except Type IV
Substrate batch size 1-25
Media flow rates
  • AZ 726 MIF (TMAH): 230 ml/min
  • Topside rinse DI water: 400 ml/min (with BSR+CR active)
  • Backside rinse DI water: 55 ml/min (with TSR+CR active)
  • Process Nitrogen: 50 l/min


Process information

Processing on Developer TMAH UV-lithography consists of the following steps:

  • Post-exposure bake
  • Puddle development
  • Rinse


Features of Developer TMAH UV-lithography:

  • Cassette-to-cassette wafer handling
  • In-line hotplates
  • In-line cool plate
  • Puddle developer module with rinse and dry


Post-exposure baking

Chemically amplified resists and cross-linking negative resists must be baked after exposure in order to finish the process initiated by the exposure light. Post-exposure bake, or PEB, is carried out on one of the two hotplates. After baking, the wafer is cooled for 20 seconds on the 20°C cool plate.

Puddle Development

Development on Developer TMAH UV-lithography is divided into the following steps:

  • Pre-wet
  • Puddle dispense
  • Development
  • Spin-off

Pre-wet may be done using developer or DI water, or it may be skipped. It consists of a short dispense at medium spin speed (2s @ 1200 rpm).

Puddle dispense is done by dispensing developer (AZ 726 MIF) to the center of the wafer in order to build up a puddle of developer on the wafer. During the dispense, the wafer may be stopped or rotating slowly (30 rpm). The developer is dispensed at a rate of approximately 225 ml/min. A dispense time of 3s, and 7s is used for 4", and 6" wafers, respectively, corresponding to a volume of 11 ml, and 26 ml, respectively.

Development is carried out by leaving the developer puddle on the wafer for the duration of the development time (puddle time). The rotation is stopped during the development, but the developer may be agitated by rotating the wafer a few turns at low speed, e.g. 2s @ 30 rpm halfway through the development time, in order to facilitate good uniformity.

Spin-off is designed to stop the development by removing the developer from the wafer before the rinse. It is usually carried out as a short spin at high speed (3s @ 4000 rpm), but may be omitted.

Processes are divided into single puddle (SP), double puddle (DP), and multiple puddle (MP).

Rinse

After development, the substrate is rinsed using DI water, and dried using nitrogen.

The standard rinse and dry procedure is 30s at 4000 rpm with DIW being administered from the top at the center of the substrate, followed by a 10-15s dry at 3000 rpm using nitrogen from the top at the center of the substrate. The top side rinse is at a rate of approximately 500 ml/min, corresponding to 250 ml DIW during the rinse. The flow rate of the nitrogen is 50 l/min, and the drying time is set according to the size of the substrate.

Process recommendations

Recommended parameters for development of different resists. Information about exposure dose can be found here: Information on UV exposure dose


2 µm AZ nLOF 2020

  • PEB: 60s @ 110°C
  • Development: SP 30s. For lift-off, use SP 60s (sidewall angle ~15°)


1.5 µm AZ MiR 701

  • PEB: 60s @ 110°C
  • Development: SP 60s


1.5 µm AZ 5214E

  • No PEB
  • Development: SP 60s


2.2 µm AZ 5214E (image reversal)

  • Reversal bake: 60s-120s @ 110°C
  • Flood exposure: ~500 mJ/cm2
  • Development: SP 60s


6.2 µm AZ 4562

  • No PEB
  • Development: MP 3x60s


10 µm AZ 4562

  • No PEB
  • Development: MP 4x60s or MP 5x60s


Standard Processes

NB: The list of standard processes is not necessarily complete, as new processes are added over time.

Development (only)

Development sequences on Developer TMAH UV-lithography are grouped in the sequence number range 1000-1999 and are divided into the following steps: Pre-wet, puddle dispense, development, spin-off, and finally rinse and dry.

Single puddle:

  • (1001) DCH 100mm SP 30s
  • (1002) DCH 100mm SP 60s
  • (1004) DCH 100mm SP 90s
  • (1003) DCH 100mm SP 120s
  • (1005) DCH 150mm SP 60s


Multiple puddle:

  • (1019) DCH 100mm MP 3x60s
  • (1010) DCH 100mm MP 4x60s
  • (1012) DCH 100mm MP 5x60s
  • (1018) DCH 100mm MP 7x60s
  • (1017) DCH 100mm MP 10x60s
  • (1006) DCH 150mm MP 3x60s


Each of these sequences start with a 2s pre-wet at 1200 rpm using developer. The puddle dispense is done at a rotation of 30rpm. The dispense time is 3s, and 7s, corresponding to a volume of 11 ml, and 26 ml, for 100mm, and 150mm, respectively. The development (puddle time) is split in two by an agitation step of 2s at 30rpm (one rotation). Spin-off is 3s at 4000rpm. Finally, the wafer is rinsed as described above. The multiple puddle sequences repeat the dispense, development, and spin off steps a number of times before the rinse.


Special sequences:

  • DCH 100mm SP 60s no spin-off


As DCH 100mm SP 60s except the spin-off step is omitted. The development is thus terminated by the rinse (30s @ 4000rpm). This may help in case of scumming problems.

Post-exposure baking (only)

Chemically amplified resists and cross-linking negative resists must be baked after exposure (Post-Exposure Bake, PEB) in order to finish the process initiated by the exposure light. The PEB sequences are grouped in the sequence number range 2000-2999:

  • (2001) DCH PEB 110C 60s
  • (2002) DCH PEB 110C 120s


The baking is done at 110°C followed by a cooling step at 20°C for 20 seconds.

Combined PEB and development

For convenience, the PEB and development function of the machine may be combined in one sequence. The PEB + development sequences are grouped in the sequence number range 3000-3999:

  • (3001) DCH 100mm PEB60s@110C+SP60s
  • (3005) DCH 100mm PEB60s@110C+SP30s
  • (3010) DCH 150mm PEB60s@110C+SP60s


The sequences are a combination of [substrate size] + [PEB at temperature and time] + [development for time].

The content on this page, including all images and pictures, was created by DTU Nanolab staff, unless otherwise stated.

Developer: TMAH UV-lithography

 
The Developer: TMAH Stepper is placed in F-3.

Tool description
This developer is dedicated for development of DUV resists. The developer is fully automatic and can run 1-25 substrates in a single batch. Supported substrate sizes are 100 mm, 150 mm and 200 mm (200 mm requires tool change). The machine is equipped with 1 developer line with 2,38% TMAH in water (AZ 726 MIF), 1 topside rinse line with DI water, 1 backside rinse line with DI water and 1 Nitrogen line for drying.

The developer dispense, puddle time, agitation, rinse and drying is controlled by the tool.

Product: Süss MicroTec Gamma 2M developer
Year of purchase: 2013
Location: Cleanroom F-3

User manual
The user manual and contact information can be found in LabManager - requires login

Tool training
Training on the tool requires users to complete the lithography TPT followed by the online tool training and a hands-on authorization training.
The tool training video is part of the online tool training, but can also be viewed here.

Equipment performance and process related parameters

Tool purpose

Development of DUV resists:

  • KrF M230Y
  • KrF M35G

May also be used for development of:

  • AZ nLOF 2020
  • AZ MIR 701
  • AZ 5214E
  • AZ 4562
Developer AZ 726 MIF (2.38% TMAH)
Development method Puddle
Handling method
  • Vacuum chuck for 100 mm & 150 mm wafers
  • Vacuum chuck for 200 mm wafers (requires tool change)
Process temperature Room temperature
Process agitation 1 cycles per 30 seconds
Process rinse DI water
Substrate sizes
  • 100 mm wafers
  • 150 mm wafers
  • 200 mm wafers (requires tool change)
Substrate materials
  • Silicon, III-V or glass substrates
  • Film, or pattern, of all materials except Type IV
Substrate batch size 1-25
Media flow rates
  • AZ 726 MIF (TMAH): 500 ml/min
  • Topside rinse DI water: 350 ml/min (with BSR+CR active)
  • Backside rinse DI water: 45 ml/min (with TSR+CR active)
  • Process Nitrogen: 50 l/min


Process information

 
The SEM picture of 250 nm pillars and lines. Exposure dose is 140 J/m2.

Processing on Developer TMAH stepper consists of the following steps:

  • Post-exposure bake
  • Puddle development
  • Rinse


Features of Developer TMAH stepper:

  • Cassette-to-cassette wafer handling
  • In-line hotplates
  • In-line cool plate
  • Puddle developer module with rinse and dry


The development process will be performed by the customer together with the Lithography group of DTU Nanolab. In case you would like to do DUV lithography please contact Lithography team, who will consult you and run your wafers together with you.

Here you can find a chart‎ demonstrating a dependence between 250 nm line width/pillars diameter and exposure dose.

Post-exposure baking

Chemically amplified resists and cross-linking negative resists must be baked after exposure in order to finish the process initiated by the exposure light. Post-exposure bake, or PEB, is carried out on one of the two hotplates. After baking, the wafer is cooled for 20 seconds on the 20°C cool plate.

Puddle Development

Development on Developer TMAH stepper is divided into the following steps:

  • Pre-wet
  • Puddle dispense
  • Development
  • Spin-off

Pre-wet may be done using developer or DI water, or it may be skipped. It consists of a short dispense at medium spin speed (2s @ 1200 rpm).

Puddle dispense is done by dispensing developer (AZ 726 MIF) to the center of the wafer in order to build up a puddle of developer on the wafer. During the dispense, the wafer may be stopped or rotating slowly (30 rpm). The developer is dispensed at a rate of approximately 500 ml/min.

Development is carried out by leaving the developer puddle on the wafer for the duration of the development time (puddle time). The rotation is stopped during the development, but the developer may be agitated by rotating the wafer a few turns at low speed, e.g. 2s @ 30 rpm halfway through the development time, in order to facilitate good uniformity.

Spin-off is designed to stop the development by removing the developer from the wafer before the rinse. It is usually carried out as a short spin at high speed (3s @ 4000 rpm), but may be omitted.

Processes are divided into single puddle (SP), double puddle (DP), and multiple puddle (MP).

Rinse

After development, the substrate is rinsed using DI water, and dried using nitrogen.

The standard rinse and dry procedure is 30s at 4000 rpm with DIW being administered from the top at the center of the substrate, followed by a 10-15s dry at 3000 rpm using nitrogen from the top at the center of the substrate. The top side rinse is at a rate of approximately 350 ml/min. The flow rate of the nitrogen is 50 l/min, and the drying time is set according to the size of the substrate.


Standard Processes

NB: The list of standard processes is not necessarily complete, as new processes are added over time.

Development (only)

Development sequences on Developer TMAH stepper are divided into the following steps: Pre-wet, puddle dispense, development, spin-off, and finally rinse and dry.

Single puddle:

  • 1004 DCH DEV 60s
  • 1104 DCH 100mm SP 60s
  • 1105 DCH 150mm SP 60s
  • 1106 DCH 200mm SP 60s


Post-exposure baking (only)

Chemically amplified resists and cross-linking negative resists must be baked after exposure (Post-Exposure Bake, PEB) in order to finish the process initiated by the exposure light:

  • (1000) DCH PEB 130C 60s
  • (1001) DCH PEB 130C 90s


The baking is done at 130°C followed by a cooling step at 20°C for 20 seconds.

Combined PEB and development

For convenience, the PEB and development function of the machine may be combined in one sequence:

  • (1002) DCH PEB_60s and DEV_60s
  • (1003) DCH PEB_90s and DEV_60s


Decommisioned tools

Developer 1 & 2 were decommissioned 2017-01. Information about decommissioned tool can be found here.

Developer 6 inch was decommissioned 2019-12. Information about decommissioned tool can be found here.