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Specific Process Knowledge/Lithography/nLOF: Difference between revisions

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*PEB temperature: 110°C
*PEB temperature: 110°C
*PEB time: 60 s
*PEB time: 60 s


The recommended PEB for nLOF is 60 seconds at 110°C, regardless of resist film thickness.
The recommended PEB for nLOF is 60 seconds at 110°C, regardless of resist film thickness.


===PEB baking time investigation===
===PEB baking time investigation===
While 60 s @ 110°C is adequate for Si substrates, less thermally conductive substrates (glass, III-V materials, chips bonded to carrier), have shown problems using the standard PEB recipe.<br>
While 60 s @ 110°C is adequate for Si substrates, less thermally conductive substrates (glass, III-V materials, chips bonded to carrier), have shown problems using the standard PEB recipe.<br>
These problems were largely solved by increasing the PEB time to 120 s. Tests (on Aligner: Maskless 02) have shown that the lithographic performance of nLOF on Si is improved when using 120 s @ 110°C PEB (less stitching, less bias, more negative profile). A small report on the tests can be found [[media:nLOF_PEBtime_2019.pdf|'''here''']].
These problems were largely solved by increasing the PEB time to 120 s. Tests (on Aligner: Maskless 02) have shown that the lithographic performance of nLOF on Si is improved when using 120 s @ 110°C PEB (less stitching, less bias, more negative profile).  
 
A small report on the tests can be found here: [[media:nLOF_PEBtime_2019.pdf|'''nLOF PEB time 2019''']].


==Development==
==Development==
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*Puddle development in 2.38% TMAH (AZ 726 MIF): ~4 µm/min
*Puddle development in 2.38% TMAH (AZ 726 MIF): ~4 µm/min


A 2 µm nLOF resist film is fully developed in ~30 s in 2.38% TMAH (AZ 726 MIF). However, the development can be continued to 60 s in order to get a more negative resist profile (due to increased under-cut).
===Solvent development===
Cross-linking negative resists have the potential to be developed using organic solvents instead of the normally used alkaline aqueous solutions. A quick test of this was carried out by Thomas Anhøj @ DTU Nanolab, showing that nLOF 2020 could potentially be used for water-free lithography.


A 2 µm nLOF resist film is fully developed in ~30 s in 2.38% TMAH (AZ 726 MIF). However, the development can be continued to 60 s in order to get a more negative resist profile (due to increased under-cut).
A small report on the test can be found here: [[media:nLOF_solventdev_2024.pdf|'''nLOF solvent development 2024''']].