Specific Process Knowledge/Lithography/MiR: Difference between revisions

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AZ MiR 701 is a positive UV photoresist.
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[[Category: Lithography|Resist]]
[[Category: Resist|AZ MiR 701]]
 
__TOC__
 
==Resist description==
AZ MiR 701 is a positive UV photoresist. It is considered to have high selectivity for dry etching.


==Spin coating==
==Spin coating==
[[Image:MiRspincurves.JPG|640px|thumb|Spin curves for AZ MiR 701 (29 cps) using a 30 s spin-off, and a 60 s @ 90°C proximity softbake]]
'''Typical spin parameters:'''
*Spin off: 30-60 s
*Soft bake: 60 s @ 90°C in proximity
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[[Image:MiRspincurves.JPG|500x500px|thumb|Spin curves for AZ MiR 701 (29cps) using a 30s spin-off, and a 60s@90°C softbake (proximity bake for Gamma)]]
==Exposure==
'''Dehydration of resist film:'''<br>
During exposure in the maskless aligners, MiR can be sensitive to dehydration by the air flow applied by the pneumatic auto-focus mechanism. This may lead to insufficient development, especially for small substrates. This problem can be alleviated by switching to the overview camera for a period of 1 minute before starting the exposure, or simply by parking the writehead away from the exposure location for 1 minute before starting the exposure.


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The effect can also be reduced by increasing the soft bake.


==Post-exposure bake==
==Post-exposure bake==
'''Typical PEB parameters:'''
*PEB temperature: 110°C
*PEB time: 60 s


During exposure, interaction between the incoming light and the light reflected by the substrate can cause a standing wave to form in the resist (especially true for single line/wavelength exposure). This leads to a wavy sidewall after development. The standing wave pattern can be removed by introducing a post-exposure bake before development, which allows the activated PAC to diffuse into un-activated regions, thus smoothing the sidewall. The recommended PEB for MiR is 60s at 110°C (1-2µm film). Thicker coatings may require longer bake, and substrate thickness and material, e.g glass, may also affect the required baking time.
During exposure, interaction between the incoming light and the light reflected by the substrate can cause a standing wave to form in the resist (especially true for single line/wavelength exposure). This leads to a wavy sidewall after development. The standing wave pattern can be removed by introducing a post-exposure bake before development, which allows the activated PAC to diffuse into unactivated regions, thus smoothing the sidewall. The recommended PEB for MiR is 60 s at 110°C (for a 1 - 2 µm film). Thicker coatings may require longer bake, and substrate thickness and material may also affect the required baking time.


As the post-exposure bake is at an elevated temperature compared to the soft bake, it will cause the resist film to become 5-10% thinner (probably due to continued evaporation of solvent). A 1.5µm thick MiR resist film will be approximately 1.4µm after PEB.
Since the post-exposure bake is at an elevated temperature compared to the soft bake, it will cause the resist film to become 5-10% thinner (probably due to continued evaporation of solvent). A 1.5 µm thick MiR resist film will be approximately 1.4 µm after PEB.


==Development==
==Development==
 
'''Development speed:'''
A 1.5-2µm MiR resist film is fully developed in 60s using TMAH (AZ 726). Depending on the exposure dose, thicker coatings may develop in 1 min, but it is probably better to aim for a similar development speed (2µm/min).
*Puddle development in 2.38% TMAH (AZ 726 MIF): ~2 µm/min

Latest revision as of 14:27, 5 April 2023

This section, including all images and pictures, is created by DTU Nanolab staff unless otherwise stated.

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Resist description

AZ MiR 701 is a positive UV photoresist. It is considered to have high selectivity for dry etching.

Spin coating

Spin curves for AZ MiR 701 (29 cps) using a 30 s spin-off, and a 60 s @ 90°C proximity softbake

Typical spin parameters:

  • Spin off: 30-60 s
  • Soft bake: 60 s @ 90°C in proximity


Exposure

Dehydration of resist film:
During exposure in the maskless aligners, MiR can be sensitive to dehydration by the air flow applied by the pneumatic auto-focus mechanism. This may lead to insufficient development, especially for small substrates. This problem can be alleviated by switching to the overview camera for a period of 1 minute before starting the exposure, or simply by parking the writehead away from the exposure location for 1 minute before starting the exposure.

The effect can also be reduced by increasing the soft bake.

Post-exposure bake

Typical PEB parameters:

  • PEB temperature: 110°C
  • PEB time: 60 s


During exposure, interaction between the incoming light and the light reflected by the substrate can cause a standing wave to form in the resist (especially true for single line/wavelength exposure). This leads to a wavy sidewall after development. The standing wave pattern can be removed by introducing a post-exposure bake before development, which allows the activated PAC to diffuse into unactivated regions, thus smoothing the sidewall. The recommended PEB for MiR is 60 s at 110°C (for a 1 - 2 µm film). Thicker coatings may require longer bake, and substrate thickness and material may also affect the required baking time.

Since the post-exposure bake is at an elevated temperature compared to the soft bake, it will cause the resist film to become 5-10% thinner (probably due to continued evaporation of solvent). A 1.5 µm thick MiR resist film will be approximately 1.4 µm after PEB.

Development

Development speed:

  • Puddle development in 2.38% TMAH (AZ 726 MIF): ~2 µm/min