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XPS technique

XPS is a surface sensitive and non destructive technique used for analysis of the elemental composition. The basic principle is shown below.

In the XPS spectrometer system the probed samples are irradiated by photons with a specific energy, and the photoelectrons that leaves the sample are detected. The energy levels of the electrons are elemental specific, and by measuring the energy of the outgoing electrons, it is possible to detect which elements that are present in a sample.

You can read further about the technique here: [1]

X-ray Photoelectron Spectroscopy analysis (XPS)

During a XPS (X-ray Photoelectron Spectroscopy) analysis, the sample is irradiated with photons of a specific energy (in the Danchip system 1486 eV). When energy of the irradiating X-rays is adsorbed by the atoms in the sample, photoelectrons are ejected [[2]].

Since the energy of the incoming photons is known, and the energy of the ejected electrons is measured, the binding energy of the electrons in the probed atoms can be determined. The binding energy of the electrons are element specific, and is therefore a "finger-print" of the atom. Hence, a measurement of the XPS spectrum gives information of which materials are present in the sample, and at which concentrations.

XPS is an excellent technique to probe the chemical state of atoms on a surface. The binding energy of lower lying atomic levels (for example 1s, 2s and 2p) are at a specific energy, but is slightly affected by the chemical environment of the probed atom. This is known as the chemical shift. By measuring the shift of the electron binding energies one can determined the chemical state of atoms. See an example on the page XPS-ThermoScientific.

Typical applications of XPS

The XPS can be used for different applications, for example:

Do an elemental analysis of the outermost layer of your surface.
Check the composition of a film at different depths.
Check for a contaminations.
- It not as sensitive as the SIMS, but faster, so it can be an alternative if you are checking for a bit higher contamination levels (like 1 %)
Do a analysis of the chemical state of atoms present on the surface.
- See what effect a surface treatment of your sample has on the surface chemistry.
- Check a polymer covered surface. Are for example (C=O), (C-OH) (C-C) groups present in the polymer after it been deposited on a surface.