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| == Development == | | == Development == |
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| = E-beam resists =
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| == Standard E-beam resists and process guidelines ==
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| DTU Nanolab offers a limited number of standard EBL resist for our users. Our standard resist and process guidelines are summarized below. CSAR (AR-P 6200.09) is installed on Spin coater Gamma E-beam & UV for easy spin coating of 2", 4" and 6" substrates. Other substrate sizes or resist have to be used in the Labspin 2/3 coating systems. The standard resist bottles are stored in the chemical cupboard in E-4.
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| {|border="1" cellspacing="1" cellpadding="3" style="text-align:left;" width="95%"
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| |-style="background:silver; color:black"
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| |'''Resist'''
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| |'''Polarity'''
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| |'''Manufacturer'''
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| |'''Comments'''
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| |'''Technical reports'''
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| |'''Spin Coater'''
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| |'''Thinner'''
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| |'''Developer'''
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| |'''Rinse'''
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| |'''Remover'''
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| |'''Process flows (in docx-format)'''
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| |-style="background:WhiteSmoke; color:black"
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| |'''[[Specific_Process_Knowledge/Lithography/CSAR|CSAR AR-P 6200]]'''
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| |Positive
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| |[http://www.allresist.com AllResist]
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| |Standard positive resist, very similar to ZEP520.
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| |[https://www.allresist.com/wp-content/uploads/sites/2/2020/03/AR-P6200_CSAR62english_Allresist_product-information.pdf AR-P 6200 info]
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| |Gamma E-beam & UV or Labspin 2/3
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| |Anisole
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| *AR-600-546
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| *AR-600-548
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| *N50
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| *MIBK:IPA
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| |IPA
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| *AR-600-71
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| *Remover 1165
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| |[[media:Process_Flow_CSAR.docx|Process Flow CSAR.docx]] <br> [[media:Process Flow CSAR ESPACER.docx|Process Flow CSAR with ESPACER]] <br> [[media:Process Flow CSAR with Al.docx|Process Flow CSAR with Al]] <br> [[media:Process_Flow_LOR5A_CSAR_Developer_TMAH_Manual.docx|Process Flow LOR5A with CSAR]] <br>
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| |-
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| |-style="background:LightGrey; color:black"
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| |'''[[Specific_Process_Knowledge/Lithography/ARN8200|Medusa AR-N 8200]]'''
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| |Negative
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| |[http://www.allresist.com AllResist]
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| |Both e-beam and DUV sensitive resist.
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| |[https://www.allresist.com/wp-content/uploads/sites/2/2020/03/SXAR-N8200-1_english_Allresist_product_information.pdf AR-N 8200 info]
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| |Labspin 2/3
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| |AR 600-07
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| |AR 300-47:DIW (1:1)
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| |DIW
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| |BOE
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| |-
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| |-style="background:LightGrey; color:black"
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| |'''AR-N 7500'''
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| |Negative
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| |[http://www.allresist.com AllResist]
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| |Both e-beam, DUV and UV-sensitive resist.
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| |[https://www.allresist.com/wp-content/uploads/sites/2/2020/03/AR-N7500_english_Allresist_product-information.pdf AR-N 7500 info]
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| |Labspin 2/3
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| |PGMEA
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| *AR 300-47:DIW (4:1)
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| *MIF726:DIW (8:5)
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| |DIW
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| *AR 300-73
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| *O2 plasma
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| |}
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| <br/>
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| == Non-Standard E-beam resists ==
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| It is possible to obtain permission to user other resists at DTU Nanolab, users must however provide these resists and possibly developers themselves. A non-exhaustive list of user supplied EBL resist used at DTU Nanolab and some process guidelines can be found in the table below.
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| {|border="1" cellspacing="1" cellpadding="3" style="text-align:left;" width="95%"
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| |-style="background:silver; color:black"
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| |'''Resist'''
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| |'''Polarity'''
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| |'''Manufacturer'''
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| |'''Comments'''
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| |'''Technical reports'''
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| |'''Spin Coater'''
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| |'''Thinner'''
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| |'''Developer'''
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| |'''Rinse'''
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| |'''Remover'''
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| |'''Process flows (in docx-format)'''
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| |-
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| |-style="background:LightGrey; color:black"
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| |'''[[Specific_Process_Knowledge/Lithography/ZEP520A|ZEP520A]]'''
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| |Positive resist, contact [mailto:Lithography@Nanolab.dtu.dk Lithography] if you plan to use this resist
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| |ZEON
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| |Positive resist
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| |[[media:ZEP520A.pdf|ZEP520A.pdf]], [[media:ZEP520A.xls|ZEP520A spin curves on SSE Spinner]]
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| |See table <u>[[Specific_Process_Knowledge/Lithography/Coaters#Coaters:_Comparison_Table|here]] </u>
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| |Anisole
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| |ZED-N50/Hexyl Acetate,n-amyl acetate, oxylene. [[media:JJAP-51-06FC05.pdf|JJAP-51-06FC05.pdf]], [[media:JVB001037.pdf|JVB001037.pdf]]
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| |IPA
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| |acetone/1165
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| |[[media:Process_Flow_ZEP.docx|Process_Flow_ZEP.docx]]
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| |-
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| |-style="background:WhiteSmoke; color:black"
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| |'''[[Specific_Process_Knowledge/Lithography/ARP617|Copolymer AR-P 617]]'''
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| |Positive
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| |[http://www.allresist.com AllResist]
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| |Approved, not tested yet. Used for trilayer (PE-free) resist-stack or double-layer lift-off resist stack. Please contact [mailto:Lithography@nanolab.dtu.dk Lithography] for information.
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| |[[media:AR_P617.pdf|AR_P617.pdf]]
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| |See table <u>[[Specific_Process_Knowledge/Lithography/Coaters#Coaters:_Comparison_Table|here]] </u>
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| |PGME
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| |AR 600-55, MIBK:IPA
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| |acetone/1165
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| |Trilayer stack: [[media:Process_Flow_Trilayer_Ebeam_Resist.docx|Process_Flow_Trilayer_Ebeam_Resist.docx]]
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| |-
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| |-style="background:LightGrey; color:black"
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| |'''[[Specific_Process_Knowledge/Lithography/mrEBL6000|mr EBL 6000.1]]'''
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| |Negative
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| |[http://http://www.microresist.de/home_en.htm MicroResist]
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| |Standard negative resist
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| |[[media:mrEBL6000 Processing Guidelines.pdf|mrEBL6000 processing Guidelines.pdf]]
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| |See table <u>[[Specific_Process_Knowledge/Lithography/Coaters#Coaters:_Comparison_Table|here]] </u>
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| |Anisole
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| |mr DEV
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| |IPA
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| |mr REM
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| |[[media:Process_Flow_mrEBL6000.docx|Process_Flow_mrEBL6000.docx]]
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| |-
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| |-style="background:WhiteSmoke; color:black"
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| |'''HSQ (XR-1541)'''
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| |Negative
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| |DOW Corning
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| |Approved. Standard negative resist
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| |[[media:DowCorningHSQA.pdf|HSQ Dow Corning]], [[media:MSDS HSQ.pdf|MSDS HSQ]]
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| |See table <u>[[Specific_Process_Knowledge/Lithography/Coaters#Coaters:_Comparison_Table|here]] </u>
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| |TMAH, AZ400K:H2O
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| |H2O
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| |[[media:Process Flow HSQ.docx|process flow HSQ]]
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| [[/High resolution patterning with HSQ|High resolution patterning with HSQ]]
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| |-
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| |-style="background:LightGrey; color:black"
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| |'''AR-N 7520'''
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| |Negative
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| |[http://www.allresist.com AllResist]
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| |Both e-beam, DUV and UV-sensitive resist. Currently being tested, contact [mailto:pxshi@dtu.dk Peixiong Shi] for information.
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| |[[media:AR-N7500-7520.pdf|AR-N7500-7520.pdf]]
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| |See table <u>[[Specific_Process_Knowledge/Lithography/Coaters#Coaters:_Comparison_Table|here]] </u>
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| |PGMEA
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| |AR 300-47, TMAH
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| |H2O
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| |-
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| |-style="background:WhiteSmoke; color:black"
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| |'''[[Specific_Process_Knowledge/Lithography/PMMA|PMMA]]'''
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| |Positive
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| | [http://www.allresist.com AllResist]
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| |We have various types of PMMA in the cleanroom. Please contact [mailto:Lithography@nanolab.dtu.dk Lithography] for information.
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| |See table <u>[[Specific_Process_Knowledge/Lithography/Coaters#Coaters:_Comparison_Table|here]] </u>
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| |Anisole
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| |MIBK:IPA (1:3), IPA:H2O
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| |IPA
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| |acetone/1165/Pirahna
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| |-
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| |-style="background:LightGrey; color:black"
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| |'''ZEP7000'''
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| |Positive
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| |ZEON
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| |Not approved. Low dose to clear, can be used for trilayer (PEC-free) resist-stack. Please contact [mailto:Lithography@nanolab.dtu.dk Lithography] for information.
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| |[[media:ZEP7000.pdf|ZEP7000.pdf]]
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| |See table <u>[[Specific_Process_Knowledge/Lithography/Coaters#Coaters:_Comparison_Table|here]] </u>
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| |Anisole
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| |ZED-500/Hexyl Acetate,n-amyl acetate, oxylene.
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| |IPA
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| |acetone/1165
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| |Trilayer stack: [[media:Process_Flow_Trilayer_Ebeam_Resist.docx|Process_Flow_Trilayer_Ebeam_Resist.docx]]
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| |}
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| <br/>
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| == User resist bottles in the cleanroom == | | == User resist bottles in the cleanroom == |