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==Oxide insulation analysis==
==Oxide insulation analysis==


The wafers in this analysis consisted of an Si substrate with no native oxide. A layer of SiO2 was reactively sputtered (9% O2 90 W 3.5 mTorr). After that, using a shadow mask, 200nm thick gold rectangles was electrodeposited on top of the oxide. Gold was also electrodeposited on the back side. Then the impedance as function of frequency was recorded.
The wafers in this analysis consisted of a Si substrate with no native oxide. A layer of SiO<math>_2</math> was reactively sputtered (9% O2 90 W 3.5 mTorr). After that, using a shadow mask, 200nm thick gold rectangles was electro deposited on top of the oxide. Gold was also electro deposited on the back side. Then the impedance as a function of frequency was recorded.


The figure shows the measurements for different oxide thicknesses. Most of the measurements show perfect capacitors, although for illustration measurements with a few pinholes and a many pinholes is also shown for the 20 nm sample.  
The figure shows the measurements for different oxide thicknesses. Most of the measurements show perfect capacitors, although for illustration measurements with a few pinholes and with many pinholes is also shown for the 20 nm sample.  


The success rate for the different thicknesses can be seen in the table, together with the number of samples measured and the number of perfect capacitors.
The success rate for the different thicknesses can be seen in the table, together with the number of samples measured and the number of perfect capacitors.


It is possible to make perfect capacitors with oxide thicknesses down to and including 5 nm and possibly even thinner, although the failure rate increases. Bear in mind, though that each structure measured here has an area of 8 mm2 - for a 1 mm2 structure the failure rate would be much lower, assuming the short circuits are not located on the sides of the structures.
It is possible to make perfect capacitors with oxide thicknesses down to and including 5 nm and possibly even thinner, although the failure rate increases. Bear in mind, though that each structure measured here has an area of 8 mm<sup>2</sup> - for a 1 mm<sup>2</sup> structure the failure rate would be much lower, assuming the short circuits are not located on the sides of the structures.