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Specific Process Knowledge/Thin film deposition/Deposition of Hafnium Oxide: Difference between revisions

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![[Specific Process Knowledge/Thin film deposition/ALD Picosun R200|ALD1]]
![[Specific Process Knowledge/Thin film deposition/ALD Picosun R200|ALD1]]
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![[Specific Process Knowledge/Thin film deposition/ALD2 (PEALD)|ALD2 (PEALD)]].
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*Atomic Layer Deposition
*Atomic Layer Deposition
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*(Plasma enhanced) Atomic Layer Deposition
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!Stoichiometry
!Stoichiometry
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*HfO2
*HfO<sub>2</sub>
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*
*HfO<sub>2</sub>
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!Film Thickness
!Film Thickness
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* 0 nm - 50 nm  
*0 nm - 100 nm  
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*0 nm - 50 nm
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!Deposition rate
!Deposition rate
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* 0.0827 nm/cycle on a flat sample
* At 150 <sup>o</sup>C: 0.11 nm/cycle
* 0.954-0.122 nm/cycle on a high aspect ratio structures
* At 250 <sup>o</sup>C: 0.0827 nm/cycle
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* At 250 <sup>o</sup>C: 0.0804 nm/cycle
* At 250 <sup>o</sup>C on trenches: 0.954-1.22 nm/cycle
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!Step coverage
!Step coverage
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*Very good.
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*Very good
*Very good
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!Process Temperature
!Temperature window
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* 150 - 300<sup>o</sup>C
*150 <sup>o</sup>C - 300 <sup>o</sup>C
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*150 <sup>o</sup>C - 300 <sup>o</sup>C
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!Substrate size
!Substrate size
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*Several small samples
*1-5 100 mm wafers (only good uniformity for the top wafer)
*1-5 50 mm wafers
*1-5 150 mm wafer (only good uniformity for the top wafer)
*1-5 100 mm wafers
*1 200 mm wafer
*1-5 150 mm wafer
*Several smaller samples
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*1 100 mm wafer
*1 150 mm wafer
*1 200 mm wafer
*Several smaller samples
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*Silicon oxide, silicon nitride
*Silicon oxide, silicon nitride
*Quartz/fused silica  
*Quartz/fused silica  
*Al, Al<sub>2</sub>O<sub>3</sub>
*Metals (use dedicated carrier wafer)
*Ti, TiO<sub>2</sub>
*Other metals (use dedicated carrier wafer)
*III-V materials (use dedicated carrier wafer)
*III-V materials (use dedicated carrier wafer)
*Polymers (depending on the melting point/deposition temperature, use carrier wafer)
*Polymers (depending on the melting point/deposition temperature, use carrier wafer)
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*Silicon
*Silicon oxide, silicon nitride
*Quartz/fused silica
*Metals (use dedicated carrier wafer)
*III-V materials (use dedicated carrier wafer)
*Polymers (depending on the melting point/deposition temperature, use carrier wafer)
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