Specific Process Knowledge/Thin film deposition/Deposition of MgO: Difference between revisions
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The characterization reveals a complex structure of the deposited layers. The best way to describe the samples is to implement the following model (shown in a figure). The MgO film contains a bottom intermediate layer with constant and relatively high electron density. On top of it, there is a main layer of MgO, where the density is a linear function of the depth. The highest density is on the bottom and the lowest at the top. The topmost layer contains moisture, where MgO | The characterization reveals a complex structure of the deposited layers. The best way to describe the samples is to implement the following model (shown in a figure). The MgO film contains a bottom intermediate layer with constant and relatively high electron density. On top of it, there is a main layer of MgO, where the density is a linear function of the depth. The highest density is on the bottom and the lowest at the top. The topmost layer contains moisture, where MgO binds carbon and water. | ||
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Appling this complexity allows fitting XRR data. Additionally, | Appling this complexity allows fitting XRR data. Additionally, this structure is also supported by XPS analysis, where the chemical shifts of Mg 1s and O 1s support the idea. | ||
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The deposition rate derived from the XRR analysis illustrated in | The deposition rate derived from the XRR analysis, as illustrated in the figure, is based on thickness measurements that include the bottom intermediate layer, main layer, and moisture. This is a more reliable way of the procedure. Ellipsometry cannot take care of such complexity and ellipsometric measurement should only be used as a guide. | ||
<gallery caption="Figure 1. Deposition rate and | <gallery caption="Figure 1. Deposition rate and sample modeling." widths="400px" heights="350px" perrow="2"> | ||
image:eves_MgO_deposition_rate_XRR_20220105.png| Deposition rate measured by ellipsometry and X-ray Reflectivity analysis. | image:eves_MgO_deposition_rate_XRR_20220105.png| Deposition rate measured by ellipsometry and X-ray Reflectivity analysis. | ||
image:eves_MgO_XRR_XPS_model_20220105.png|MgO sample model. | image:eves_MgO_XRR_XPS_model_20220105.png|MgO sample model. | ||