Specific Process Knowledge/Lithography/5214E: Difference between revisions

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==Development==
==Development==
 
'''Development speed in 2.38% TMAH (AZ 726 MIF):''' ~2 µm/min
A 1.5-2.2µm AZ 5214E resist film is fully developed in 60s using TMAH (AZ 726). Depending on the exposure dose, thicker coatings may develop in 1 min, but it is probably better to aim for a similar development speed (2µm/min).

Revision as of 15:46, 30 January 2023

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AZ 5214E is a positive UV photoresist with image reversal capability.

Spin coating

Spin curves for AZ 5214E using a 30s spin-off, and a 60s@90°C softbake

Spin off: 30-60s.

Soft bake: 60s @ 90°C.


Image reversal

If 5214E is baked after exposure, the exposed resist will cross-link, making it insoluble in the developer. This is called the "Reversal bake", or sometimes the post-exposure bake. The reversal bake activates cross-linking of the exposed areas, which "reverses" the polarity of the design.

If the substrate is flood exposed after the reversal bake, the previously unexposed areas become soluble, and will be removed in the subsequent development. The reversal procedure effectively makes AZ 5214E a negative resist.

The image reversal process greatly increases the sensitivity of AZ 5214E, and the dose of the image exposure is a critical parameter, especially if negative angled resist sidewalls are desired.
Half dose of the normal, positive process is a good starting point for optimization. Similarly, the reversal bake is also a critical step, and must be tightly controlled in order to achieve consistent results. If negative sidewalls are desired, 60-120s at 110°C is recommended (as well as a resist thickness above 2 µm), but if straight sidewalls are desired, 60-120s at 120°C can be used.

The flood exposure, on the other hand, is uncritical, and 2-5 times the normal positive process dose is generally used.

Development

Development speed in 2.38% TMAH (AZ 726 MIF): ~2 µm/min