Specific Process Knowledge/Thin film deposition/Deposition of Tantalum: Difference between revisions
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<i> Unless otherwise stated, this page is written by <b>DTU Nanolab internal</b></i> | |||
=Tantalum (Ta)= | |||
Tantalum (Ta) is a refractory metal prized for its extreme melting point, corrosion resistance, and biocompatibility, serving an array of semiconductor, optical, and engineering roles. | |||
Thin films are produced mainly by magnetron sputtering or e‑beam evaporation; process conditions determine whether low‑resistivity α‑Ta (stable body‑centered‑cubic) or high‑resistivity β‑Ta (metastable tetragonal) is obtained. | |||
In semiconductor fabrication, Ta acts as an adhesion liner and Cu diffusion barrier in interconnects, a robust gate or contact metal, and a hard mask, with α‑Ta preferred when minimal resistive loss is essential. | |||
Crucially, α‑Ta becomes superconducting below ≈4.5 K, making it valuable for superconducting nanowire detectors, qubit circuitry, and low‑loss microwave resonators. In contrast, the intrinsically stressed β-Ta phase is leveraged for thin-film precision resistors, microheaters, and radiation-hard sensors. | |||
Both phases benefit from Ta’s chemical inertness and x‑ray opacity, supporting x‑ray/EUV optics, MEMS springs, biomedical implants, and durable corrosion‑resistant coatings, underscoring Ta’s versatility when a stable, tunable metallic film is required. | |||
== Tantalum deposition == | == Tantalum deposition == | ||
Tantalum can be deposited by e-beam evaporation and sputter deposition. In the chart below you can compare the different deposition equipment. | Tantalum can be deposited by e-beam evaporation and sputter deposition. In the chart below you can compare the different deposition equipment. | ||
==Sputtering of Tantalum in Sputter-System Metal-Nitride(PC3)== | |||
*[[Specific_Process_Knowledge/Thin_film_deposition/Deposition_of_Tantalum/Sputtering of Ta in Sputter-System Metal-Nitride-PC3|Sputtering of Ta in Sputter-System Metal-Nitride(PC3)]]. (Recommended approach) | |||
==Sputtering of Tantalum in Sputter-System (Lesker)== | |||
*[[Specific_Process_Knowledge/Thin_film_deposition/Deposition_of_Tantalum/Sputtering of Ta|Sputtering of Ta in Sputter-System (Lesker)]]. | |||
== E-beam evaporation of Tantalum == | |||
Tantalum can be deposited by e-beam evaporation in our two Temescal tools. | |||
*[[/Ta Ebeam evaporation in Temescal |E-beam evaporation of Ta in Temescal]] | |||
<!----> | |||
{| border="1" cellspacing="0" cellpadding="4" | {| border="1" cellspacing="0" cellpadding="4" | ||
| Line 10: | Line 37: | ||
! | ! | ||
! E-beam evaporation ([[Specific Process Knowledge/Thin film deposition/Temescal|Temescal]]) | ! E-beam evaporation ([[Specific Process Knowledge/Thin film deposition/Temescal|Temescal]] and [[Specific Process Knowledge/Thin film deposition/10-pocket e-beam evaporator|E-beam evaporator (10-pockets)]]) | ||
! Sputter ([[Specific_Process_Knowledge/Thin_film_deposition/Lesker|Lesker]]) | ! Sputter ([[Specific_Process_Knowledge/Thin_film_deposition/Lesker|Lesker]]) | ||
! Sputter deposition ([[Specific Process Knowledge/Thin film deposition/Cluster-based multi-chamber high vacuum sputtering deposition system|Sputter-system Metal-Oxide (PC1) and Sputter-system Metal-Nitride (PC3)]]) | |||
|- | |- | ||
|-style="background:WhiteSmoke; color:black" | |-style="background:WhiteSmoke; color:black" | ||
| Line 17: | Line 45: | ||
| E-beam deposition of Ta | | E-beam deposition of Ta | ||
(line-of-sight deposition) | (line-of-sight deposition) | ||
| Sputter deposition of Ta | |||
(not line-of-sight) | |||
| Sputter deposition of Ta | | Sputter deposition of Ta | ||
(not line-of-sight) | (not line-of-sight) | ||
| Line 23: | Line 53: | ||
|-style="background:LightGrey; color:black" | |-style="background:LightGrey; color:black" | ||
! Pre-clean | ! Pre-clean | ||
|Ar ion source | |Ar ion source (E-beam evaporator Temescal only) | ||
|none | |||
|RF Ar clean | |RF Ar clean | ||
|- | |- | ||
|-style="background:WhiteSmoke; color:black" | |-style="background:WhiteSmoke; color:black" | ||
! Layer thickness | ! Layer thickness | ||
|10Å to 0. | |10Å to 0.2 µm* | ||
|10Å to | |10Å to 6000Å | ||
|10Å to 6000Å | |||
|- | |- | ||
|-style="background:LightGrey; color:black" | |-style="background:LightGrey; color:black" | ||
! Deposition rate | ! Deposition rate | ||
|0.5Å/s to | |0.5Å/s to 1Å/s | ||
|~0.3Å/s | |~0.3Å/s | ||
|at least in the range 1 Å/s to 4 Å/s | |||
|- | |- | ||
|-style="background:WhiteSmoke; color:black" | |-style="background:WhiteSmoke; color:black" | ||
| Line 46: | Line 79: | ||
*1x4" wafer or | *1x4" wafer or | ||
*1x6" wafer | *1x6" wafer | ||
| | |||
*Pieces or | |||
*10x4" wafer or | |||
*10x6" wafer | |||
|- | |- | ||
| Line 62: | Line 99: | ||
*See also the [http://labmanager.dtu.dk/function.php?module=XcMachineaction&view=edit&MachID=429 cross-contamination sheet] | *See also the [http://labmanager.dtu.dk/function.php?module=XcMachineaction&view=edit&MachID=429 cross-contamination sheet] | ||
| | |||
* Silicon | |||
* Silicon oxide | |||
* Silicon nitride | |||
* Silicon (oxy)nitride | |||
* Photoresist | |||
* PMMA | |||
* Mylar | |||
* SU-8 | |||
* Metals | |||
* Carbon | |||
| | | | ||
* Silicon | * Silicon | ||
| Line 76: | Line 124: | ||
|-style="background:WhiteSmoke; color:black" | |-style="background:WhiteSmoke; color:black" | ||
! Comment | ! Comment | ||
| | | Tantalum deposition heats the chamber* | ||
| | Heating to 250 °C available in the 10-pocket e-beam evaporator. | ||
| 2-inch Ta target. | |||
| 3-inch Ta target. | |||
Heating available to 600 °C. | |||
|} | |} | ||
'''*''' ''If | '''*''' ''The max thickness is limited to 200 nm as Ta deposition heats the chamber. If you wish to deposit more than that, it has to be done in several steps. The temperature on the back of a Si wafer rose to above 160 °C during deposition of 40 nm Ta even when using a cooling plate. If you wish to e-beam deposit Ta, please contact the [mailto:thinfilm@nanolab.dtu.dk Thin film group].'' | ||
Latest revision as of 09:01, 28 August 2025
Feedback to this page: click here
Unless otherwise stated, this page is written by DTU Nanolab internal
Tantalum (Ta)
Tantalum (Ta) is a refractory metal prized for its extreme melting point, corrosion resistance, and biocompatibility, serving an array of semiconductor, optical, and engineering roles. Thin films are produced mainly by magnetron sputtering or e‑beam evaporation; process conditions determine whether low‑resistivity α‑Ta (stable body‑centered‑cubic) or high‑resistivity β‑Ta (metastable tetragonal) is obtained. In semiconductor fabrication, Ta acts as an adhesion liner and Cu diffusion barrier in interconnects, a robust gate or contact metal, and a hard mask, with α‑Ta preferred when minimal resistive loss is essential. Crucially, α‑Ta becomes superconducting below ≈4.5 K, making it valuable for superconducting nanowire detectors, qubit circuitry, and low‑loss microwave resonators. In contrast, the intrinsically stressed β-Ta phase is leveraged for thin-film precision resistors, microheaters, and radiation-hard sensors. Both phases benefit from Ta’s chemical inertness and x‑ray opacity, supporting x‑ray/EUV optics, MEMS springs, biomedical implants, and durable corrosion‑resistant coatings, underscoring Ta’s versatility when a stable, tunable metallic film is required.
Tantalum deposition
Tantalum can be deposited by e-beam evaporation and sputter deposition. In the chart below you can compare the different deposition equipment.
Sputtering of Tantalum in Sputter-System Metal-Nitride(PC3)
- Sputtering of Ta in Sputter-System Metal-Nitride(PC3). (Recommended approach)
Sputtering of Tantalum in Sputter-System (Lesker)
E-beam evaporation of Tantalum
Tantalum can be deposited by e-beam evaporation in our two Temescal tools.
| E-beam evaporation (Temescal and E-beam evaporator (10-pockets)) | Sputter (Lesker) | Sputter deposition (Sputter-system Metal-Oxide (PC1) and Sputter-system Metal-Nitride (PC3)) | |
|---|---|---|---|
| General description | E-beam deposition of Ta
(line-of-sight deposition) |
Sputter deposition of Ta
(not line-of-sight) |
Sputter deposition of Ta
(not line-of-sight) |
| Pre-clean | Ar ion source (E-beam evaporator Temescal only) | none | RF Ar clean |
| Layer thickness | 10Å to 0.2 µm* | 10Å to 6000Å | 10Å to 6000Å |
| Deposition rate | 0.5Å/s to 1Å/s | ~0.3Å/s | at least in the range 1 Å/s to 4 Å/s |
| Batch size |
|
|
|
| Allowed materials |
|
|
|
| Comment | Tantalum deposition heats the chamber*
Heating to 250 °C available in the 10-pocket e-beam evaporator. |
2-inch Ta target. | 3-inch Ta target.
Heating available to 600 °C. |
* The max thickness is limited to 200 nm as Ta deposition heats the chamber. If you wish to deposit more than that, it has to be done in several steps. The temperature on the back of a Si wafer rose to above 160 °C during deposition of 40 nm Ta even when using a cooling plate. If you wish to e-beam deposit Ta, please contact the Thin film group.