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==Imprinting==
'''Feedback to this page''': '''[mailto:labadviser@danchip.dtu.dk?Subject=Feed%20back%20from%20page%20http://labadviser.danchip.dtu.dk/index.php/Specific_Process_Knowledge/Imprinting click here]'''
 
__TOC__
 
= Nano Imprint Lithography =
   
   
Imprinting (hot embossing) is a parallel transfer of a pattern made by a serial technique (often e-beam). First a stamp is made, usually in Si or SiO<math>\rm{_2}</math> however other materials could also be used. The pattern on the stamp is then transferred to a polymer (on a different substrate), by heating both stamp and substrate to above the glass transition temperature T<math>_g</math> of the polymer and then pressing the stamp and the substrate together, hence deforming the polymer on the substrate. The stamp and substrate are then cooled down and only separated when the temperature is well below T<math>_g</math> of the polymer. Normally the stack is often cooled to room temperature to easily separate the two parts.
Nano Imprint Lithography, similar to Hot Embossing, is a parallel transfer of a pattern made by a serial technique (often e-beam). First a stamp is made, usually in Si or SiO<math>\rm{_2}</math> however other materials could also be used. The pattern on the stamp is then transferred to a polymer (on a different substrate), by heating both stamp and substrate to above the glass transition temperature T<math>_g</math> of the polymer and then pressing the stamp and the substrate together, hence deforming the polymer on the substrate. The stamp and substrate are then cooled down and only separated when the temperature is well below T<math>_g</math> of the polymer. Normally the stack is often cooled to room temperature to easily separate the two parts.
 
[[File:Imprint schematic new.png|thumb|Illustration of the hot embossing process.]]


After the stamp has been removed it is possible to use the polymer as e.g. an etch mask in a dry etch to transfer the patters from the stamp to the substrate.
After the stamp has been removed it is possible to use the polymer as e.g. an etch mask in a dry etch to transfer the patters from the stamp to the substrate.
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It is necessary to deposit anti stiction coating on the stamp to ensure that it can be separated from the substrate, this is done in either the MVD or the ASE. If the stamp it not anti stiction coated it is likely that either (or both) the stamp and substrate will break during separation. It is only necessary to deposit anti stiction coating on the stamp one time even though it is used a multiple of times.
It is necessary to deposit anti stiction coating on the stamp to ensure that it can be separated from the substrate, this is done in either the MVD or the ASE. If the stamp it not anti stiction coated it is likely that either (or both) the stamp and substrate will break during separation. It is only necessary to deposit anti stiction coating on the stamp one time even though it is used a multiple of times.


==Stamp for imprint==
== Stamp for imprint ==
 
A stamp for imprint lithography is usually made in Si or SiO, however other materials could also be used.
A stamp for imprint lithography is usually made in Si or SiO, however other materials could also be used.
Here is a process flow for stamp made of SU8 resist.
Here is a process flow for stamp made of SU8 resist.[[Media:Stamp Fabrication.docx| Stamp fabrication flow.]]
 
==Imprint resist==
 
{|border="1" cellspacing="1" cellpadding="3" style="text-align:left;" width="95%"
|-
 
|-
|-style="background:silver; color:black"
|'''Resist'''
|'''Manufacturer'''
|'''Comments'''
|'''Technical reports'''
|'''Thinner'''
|'''Spinner'''
|'''Rinse'''
|'''Process flows (in docx-format)'''
 
|-
 
 


|-
<!--
|-style="background:WhiteSmoke; color:black"
= Imprint resist =
|'''Topas'''
{{:Specific Process Knowledge/Lithography/Resist/NILresist
| [http://www.microresist.de/en/products/nanoimprint-resists/thermal-nanoimprint-lithography/mr-i-t85-series micro resist technology]
!-->
|Users may purchase own resist.
|[[media:PI_mr_I_T85_2017.pdf|Topas.pdf]]
|
|LabSpin03 or LabSpin03
|IPA
|


|-
==Imprinting Parameters==
|-style="background:LightGrey; color:black"
|'''mr-I 7030R'''
| [http://www.microresist.de/en/products/nanoimprint-resists/thermal-nanoimprint-lithography/mr-i-7000r-series micro resist technology]
|We purchase only mr-I 7030R, for use it please contact [mailto:Lithography@nanolab.dtu.dk Lithography].
|[[media:PI_mr_I_7000R_8000R_2017.pdf|mr-I 7030R.pdf]]
|mr-T 1050
|LabSpin03 or LabSpin03
|Acetone
|Preparation substrate with mr-I 7030R: [[media:Imrinting_layer_spinning.docx‎ |Preparation substrate‎ with imprint layer]]


|}
When you do an imprint you may consider 3 most important parameters: pressure, temperature and imprinting time. All those  parameters are depending of printable resists molecular weight and its glas transition temperature.


== Choose an equipment ==
== Choose an Equipment ==
*[[Specific Process Knowledge/Thin_film_deposition/MVD|MVD]] - ''Molecular Vapor Deposition - Antistiction coater for silicon stamps''
*[[Specific_Process_Knowledge/Lithography/NanoImprintLithography#EVG_NIL|Imprinter 01]] - ''Tool to Imprint''
*[[Specific Process Knowledge/Thin_film_deposition/MVD|MVD]] - Molecular Vapor Deposition - ''Tool to deposit an antistiction coating for silicon or metal stamps''
*[[Specific Process Knowledge/Characterization/Drop Shape Analyzer|Drop Shape Analyzer]] - ''Tool to measure the hydrophobicity of the antistiction layer''
*[[Specific Process Knowledge/Characterization/Drop Shape Analyzer|Drop Shape Analyzer]] - ''Tool to measure the hydrophobicity of the antistiction layer''
*[[Specific_Process_Knowledge/Lithography/NanoImprintLithography#EVG_NIL|Imprinter 01]] - ''Tool to imprint''

Latest revision as of 16:25, 10 June 2025

The content on this page, including all images and pictures, was created by DTU Nanolab staff, unless otherwise stated.

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Nano Imprint Lithography

Nano Imprint Lithography, similar to Hot Embossing, is a parallel transfer of a pattern made by a serial technique (often e-beam). First a stamp is made, usually in Si or SiO2 however other materials could also be used. The pattern on the stamp is then transferred to a polymer (on a different substrate), by heating both stamp and substrate to above the glass transition temperature Tg of the polymer and then pressing the stamp and the substrate together, hence deforming the polymer on the substrate. The stamp and substrate are then cooled down and only separated when the temperature is well below Tg of the polymer. Normally the stack is often cooled to room temperature to easily separate the two parts.

Illustration of the hot embossing process.

After the stamp has been removed it is possible to use the polymer as e.g. an etch mask in a dry etch to transfer the patters from the stamp to the substrate.

It is necessary to deposit anti stiction coating on the stamp to ensure that it can be separated from the substrate, this is done in either the MVD or the ASE. If the stamp it not anti stiction coated it is likely that either (or both) the stamp and substrate will break during separation. It is only necessary to deposit anti stiction coating on the stamp one time even though it is used a multiple of times.

Stamp for imprint

A stamp for imprint lithography is usually made in Si or SiO, however other materials could also be used. Here is a process flow for stamp made of SU8 resist. Stamp fabrication flow.


Imprinting Parameters

When you do an imprint you may consider 3 most important parameters: pressure, temperature and imprinting time. All those parameters are depending of printable resists molecular weight and its glas transition temperature.

Choose an Equipment

  • Imprinter 01 - Tool to Imprint
  • MVD - Molecular Vapor Deposition - Tool to deposit an antistiction coating for silicon or metal stamps
  • Drop Shape Analyzer - Tool to measure the hydrophobicity of the antistiction layer