LabAdviser/Technology Research/Fabrication of Hyperbolic Metamaterials using Atomic Layer Deposition: Difference between revisions

'''Feedback to this page''': '''[mailto:labadviser@nanolab.dtu.dk?Subject=Feed%20back%20from%20page%20http://labadviser.nanolab.dtu.dk/index.php/LabAdviser/Technology_Research/Fabrication_of_Hyperbolic_Metamaterials_using_Atomic_Layer_Deposition click here]'''

 

 

*'''Project responsible: Evgeniy Shkondin <br>  [[image:orcid_16x16.png|16x16px]]https://orcid.org/0000-0002-8347-1814'''

*'''Partners involved:''' DTU Fotonik, DTU Nanolab (former DTU Danchip)

[[image:HMM_implementation_topology.png|600px|thumb|Figur 1. Schematics of (a) a multilayer and (b) a nanowire hyperbolic metamaterial.]]

This project deals with the technological development, design, and fabrication of hyperbolic metamaterials (HMMs) - one of the most unusual classes of artificial electromagnetic subwavelength structures. Electrodynamically, HMMs are described by a dielectric permittivity tensor " with components of opposite signs (e.g. <math>\varepsilon_{x}=\varepsilon_{y}<0, \varepsilon_{z}>0</math> ). HMMs possess unusually high wavevector, the optical density of states, and anisotropy, leading to a wide variety of potential applications such as broadband enhancement in the spontaneous emission for a single photon source, subwavelength imaging, sensing, thermal engineering, and steering of optical signals. HMMs have a potential to be a robust and versatile multi-functional platform for nanophotonics in the broad range of operating wavelengths from visible to THz regions and even at microwave region. Despite the proposed architecture of hyperbolic medium, which geometry includes simple metal/dielectric multilayers (Figure 1a) and metallic wires (Figure 1b) incorporated in dielectric host, the fabrication is still challenging, since ultrathin, continuous, pinhole free nanometer-scale coatings are desired.<br>

 

The required high-quality thin layers have been fabricated using atomic layer deposition (ALD). It is a relatively new, cyclic, self-limiting thin film deposition technology allowing thickness control on the atomic scale. As the deposition relies on a surface reaction, conformal pinhole free films can be deposited on various substrates with advanced topology. This method has been a central theme of the project and a core fabrication technique of plasmonic and dielectric metamaterial

components.<br>

 

The deposition characteristics of the simplest and most studied ALD processes, Al₂O₃ and TiO₂ were studied as a starting point. Later, the growth and characterization of ZnO semiconductor and Cu metal have been explored.<br>

 

 

arrays. The challenge of Si template fabrication using DRIE and isolation of the final structures using selective Si etch were addressed.<br>

 

Fabrication of HMMs requires the implementation of plasmonic components and traditionally noble metals are used for such purposes due to their abundant free electrons in the conduction band. However, their large real and imaginary parts of the permittivity, especially in the infrared range, result in high loss and weak confinement to the surface. Additionally, the most implemented metals in plasmonics such as Au and Ag are difficult to pattern at nanoscale due to their limited chemistry, adhesion or oxidation issues. Therefore the implementation of alternative plasmonic materials suitable for certain wavelength range has been the focus of this work.<br>

 

Transparent conductive oxides such as Al-doped ZnO (AZO) have attracted significant attention as alternative plasmonic materials, due to their low loss and metallic behavior in the near/mid-infrared range. One more advantage of AZO is the possibility of tuning the permittivity by design, by deciding the dopants or the ratio of different components, thus constituting an advantage over metals having fixed permittivity values. AZO was chosen since the Cu ALD showed up to be far less successful in terms of reproducibility and conformality requirements. AZO has been grown on different substrates in the temperature range 150 ^oC - 250 ^oC and optical, electrical and physical properties have been clarified.<br>

 

Finally, metamaterials with two different geometries have been realized, AZO trenches and AZO pillars standing in a dielectric host (air or Si). Furthermore, it has been proposed that high aspect ratio grating structures with AZO lamellas in a silicon matrix function as a versatile platform supporting both surface and volume infrared waves. By selective etching of Si the performance of the whole structure

can be reconfigured. In other words, a bi-slab HMM has been suggested, where the effective properties of the structure are controlled by the thickness of the top slab (etching depth).<br clear="all" />

 

image:AZO_Si_trench_SEM.jpg| AZO trenches in Si host. SEM image, bird-eye-view.

 

 

 

<gallery caption="Optical performance of fabricated metamaterials based on Al-doped ZnO (AZO)" widths="500px" heights="500px" perrow="4">

image:22.jpg| AZO trenches in air host. Enters hyperbolic regime for <math>\lambda>2.71 \mu m </math>

image:11.jpg| AZO trenches in Si host. Enters hyperbolic regime for <math>\lambda>7.45 \mu m </math>

image:33.jpg| AZO pillars in Si host. Metamaterial with high anisotropy in permittivity (not HMM).

image:44.jpg| AZO pillars in Si host. Metamaterial with high anisotropy in permittivity (not HMM).

<br clear="all" />

 

 

 

 

 

 

 

 

 

 

S. Zhukovsky, A. Andryieuski, O. Takayama, <u>E. Shkondin</u>, R. Malureanu, F. Jensen, & A. Lavrinenko

(2015). Physical Review Letters, 115(17), 177402  [http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.115.177402 LINK]