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==Etching of Chromium==
==Etching of Chromium==
[[Image:fumehoodetch-chrom.jpg|300x300px|thumb|Fume hood: positioned in cleanroom 2. <br />Wet Etch of Chromium can take place in a beaker in this fume hood]]
Etching of chromium is done wet at Danchip making your own set up in a beaker in a fume hood - preferably in cleanroom 2 or 4. We have two solution for this:


# HNO<math>_3</math>:H<math>_2</math>O:cerisulphate  - 90ml:1200ml:15g - standard at Danchip
Etching of chromium can be done either by wet etch, dry etch or by sputtering with ions.
# Commercial chromium etch
*[[Specific Process Knowledge/Etch/Wet Chromium Etch|Etching of Cr by wet etch]]
*[[Specific Process Knowledge/Etch/ICP Metal Etcher/Chromium|Etching of Cr by ICP metal]]
*[[Specific_Process_Knowledge/Etch/IBE&frasl;IBSD Ionfab 300|Sputtering of Cr]]
<br clear="all" />


Etch rate are depending on the level of oxidation of the metal.
==Comparison of Chromium Etch Methods==


{|border="1" cellspacing="1" cellpadding="3" style="text-align:left;"
|-


{| border="1" cellspacing="0" cellpadding="4" align="left"
!
! Chromium etch 1
! Chromium etch 2
|-
| '''General description'''
|
Etch of chromium
|
Etch of chromium
|-
|-
| '''Chemical solution'''
|-style="background:silver; color:black"
|HNO<math>_3</math>:H<math>_2</math>O:cerisulphate  - 90ml:1200ml:15g
!
|Commercial chromium etch
![[Specific Process Knowledge/Etch/Wet Chromium Etch|Cr wet etch]]
CE 8002-A
![[Specific_Process_Knowledge/Etch/ICP_Metal_Etcher|ICP metal]]
![[Specific_Process_Knowledge/Etch/IBE&frasl;IBSD Ionfab 300|IBE (Ionfab300+)]]
![[Specific_Process_Knowledge/Etch/DRIE-Pegasus/Pegasus-2|DRIE-Pegasus 2]]
|-
|-
| '''Process temperature'''
|Room temperature


|Room temperature
|-
|-style="background:WhiteSmoke; color:black"
!General description
|Wet etch of Cr premixed (Chrome etch 18)
|Dry plasma etch of Cr
|Sputtering of Cr - pure physical etch
|Primarily shallow dry etching of silicon but also thin layers of SiO2, TaO2 and Cr
|-


|-
|-
 
|-style="background:LightGrey; color:black"
| '''Possible masking materials'''
!Etch rate range
|
|
Photoresist (1.5 µm AZ5214E)
*~150nm/min at room temperature
|
|
Photoresist (1.5 µm AZ5214E)
*~14 nm/min (depending on features size and etch load)  
|
*~30nm/min (not tested yet)
|
* very slow
|-
 
|-
|-
|'''Etch rate'''
|-style="background:WhiteSmoke; color:black"
!Etch profile
|
|
~40-100 nm/min
*Isotropic
|
|
~10-20 nm/min
*Anisotropic (vertical sidewalls)
|
*Anisotropic (angles sidewalls, typical around 70 dg)
|
*Anisotropic (vertical sidewalls)
|-
 
|-
|-
|'''Batch size'''
|-style="background:LightGrey; color:black"
!Substrate size
|
*Any size and number that can go inside the beaker in use
|
|
1-25 wafers at a time
* 150 mm wafers
* Smaller wafers or pieces on a 150 mm carrier wafer
|
|
1-25 wafer at a time
Smaller pieces glued to carrier wafer
* 50mm wafer
* 100mm wafer
* 150mm wafer
* 200mm wafer
|
* 150mm wafer
* Smaller wafers or pieces on 150mm carrier
|-
|-
|'''Size of substrate'''
 
|-
|-style="background:WhiteSmoke; color:black"
!Allowed materials
|
|
4" wafers
No restrictions cross contamination wise as long as you use the right beaker and make sure that they are safe to enter in the chemicals
|
|
4" wafers
*Silicon
|-
*Quartz/fused silica
|'''Allowed materials'''
*Photoresist/e-beam resist
*PolySilicon,
*Silicon oxide
*Silicon (oxy)nitride
*Aluminium
*Titanium
*Chromium
|
|
No restrictions.
*Silicon
Make a note on the beaker of which materials have been processed.
*Silicon oxides
*Silicon nitrides
*Metals from the +list
*Metals from the -list
*Alloys from the above list
*Stainless steel
*Glass
*III-V materials
*Resists
*Polymers
*Capton tape
|
|
No restrictions.
* Silicon
Make a note on the beaker of which materials have been processed.
* Silicon oxides
* Silicon nitrides
* Thin layers of Cr, TaO2
|-
|-
|}
|}

Latest revision as of 10:33, 8 April 2026

Unless anything else is stated, everything on this page, text and pictures are made by DTU Nanolab.

All links to Kemibrug (SDS) and Labmanager Including APV and QC requires login.

Feedback to this page: click here


Etching of Chromium

Etching of chromium can be done either by wet etch, dry etch or by sputtering with ions.


Comparison of Chromium Etch Methods

Cr wet etch ICP metal IBE (Ionfab300+) DRIE-Pegasus 2
General description Wet etch of Cr premixed (Chrome etch 18) Dry plasma etch of Cr Sputtering of Cr - pure physical etch Primarily shallow dry etching of silicon but also thin layers of SiO2, TaO2 and Cr
Etch rate range
  • ~150nm/min at room temperature
  • ~14 nm/min (depending on features size and etch load)
  • ~30nm/min (not tested yet)
  • very slow
Etch profile
  • Isotropic
  • Anisotropic (vertical sidewalls)
  • Anisotropic (angles sidewalls, typical around 70 dg)
  • Anisotropic (vertical sidewalls)
Substrate size
  • Any size and number that can go inside the beaker in use
  • 150 mm wafers
  • Smaller wafers or pieces on a 150 mm carrier wafer

Smaller pieces glued to carrier wafer

  • 50mm wafer
  • 100mm wafer
  • 150mm wafer
  • 200mm wafer
  • 150mm wafer
  • Smaller wafers or pieces on 150mm carrier
Allowed materials

No restrictions cross contamination wise as long as you use the right beaker and make sure that they are safe to enter in the chemicals

  • Silicon
  • Quartz/fused silica
  • Photoresist/e-beam resist
  • PolySilicon,
  • Silicon oxide
  • Silicon (oxy)nitride
  • Aluminium
  • Titanium
  • Chromium
  • Silicon
  • Silicon oxides
  • Silicon nitrides
  • Metals from the +list
  • Metals from the -list
  • Alloys from the above list
  • Stainless steel
  • Glass
  • III-V materials
  • Resists
  • Polymers
  • Capton tape
  • Silicon
  • Silicon oxides
  • Silicon nitrides
  • Thin layers of Cr, TaO2