Specific Process Knowledge/Thin film deposition/PECVD/Doping: Difference between revisions
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'''Feedback to this page''': '''[mailto:labadviser@ | '''Feedback to this page''': '''[mailto:labadviser@nanolab.dtu.dk?Subject=Feed%20back%20from%20page%20http://labadviser.nanolab.dtu.dk/index.php/Specific_Process_Knowledge/Thin_film_deposition/PECVD/Doping click here]''' | ||
<span style="color:#FF0000">This work has been done on PECVD2. PECVD2 has been decomissioned but we keep this information because we expect PECVD3 and PECVD4 to behave similar</span> | |||
==Boron-doping by use of BSG glass deposited in PECVD2== | |||
''Results from Joachim Dahl Thomsen, Nanotech, 2014'' | |||
= | ===Recipe=== | ||
{| border="1" cellspacing="0" cellpadding="7" width="800" style="text-align:center;" | |||
|- | |||
|Recipe name | |||
|SiH<sub>4</sub> flow [sccm] | |||
|N<sub>2</sub>O flow [sccm] | |||
|N2 flow [sccm] | |||
|B<sub>2</sub>H<sub>6</sub> flow [sccm] | |||
|PH<sub>3</sub> flow [sccm] | |||
|Pressure [mTorr] | |||
|Power [W] | |||
|Description | |||
|- | |||
|1PBSG | |||
|17 | |||
|1600 | |||
|0 | |||
|120, 130, 140, 160, 240 | |||
|0 | |||
|400 | |||
|380 | |||
|BSG glass for driving in boron in Silicon | |||
|} | |||
5 tests were made where only the B<sub>2</sub>H<sub>6</sub> flow was changed for each deposition (120sccm,130sccm,140sccm,160sccm,240sccm). All deposition times were 2 min, resulting in 440 nm Oxide. | |||
The wafers were annealed in Anneal Oxide Furnace (C1) at 1000°C for 85 min to drive in the boron and the oxide was subsequently etched in BHF. | |||
The wafers were then analyzed by SIMS and the results are shown in the figure below: | |||
[[image:SIMS2.png|627x424px|left|thumb|Boron concentration measured by SIMS. Results from Joachim Dahl Thomsen, Nanotech, 2014.]] | |||
<br clear="all" /> | |||
==Boron-doping by use of BSG glass deposited in PECVD2== | |||
''Results from Trine Holm Christensen, Space, Feb. 2015'' | |||
===Recipe=== | ===Recipe=== | ||
{| border="1" cellspacing="0" cellpadding="7" | {| border="1" cellspacing="0" cellpadding="7" width="800" style="text-align:center;" | ||
|- | |- | ||
|Recipe name | |Recipe name | ||
| | |SiH<sub>4</sub> flow [sccm] | ||
|N<sub>2</sub>O flow [sccm] | |N<sub>2</sub>O flow [sccm] | ||
|N2 flow [sccm] | |N2 flow [sccm] | ||
| | |B<sub>2</sub>H<sub>6</sub> flow [sccm] | ||
|PH<sub>3</sub> flow [sccm] | |||
|Pressure [mTorr] | |Pressure [mTorr] | ||
|Power [W] | |Power [W] | ||
| Line 22: | Line 62: | ||
|1600 | |1600 | ||
|0 | |0 | ||
| | |120, 130, 140 | ||
| | |0 | ||
| | |400 | ||
| | |380 | ||
|BSG glass for driving in boron in Silicon | |||
|} | |} | ||
3 tests were made where only the B<sub>2</sub>H<sub>6</sub> flow was changed for each deposition (120sccm,130sccm,140sccm,160sccm,240sccm). All deposition times were 2 min, resulting in approximately 400nm Oxide. | |||
The wafers were going through several annealing and oxidation step: | |||
'''The total thermal budget for the wafers:''' | |||
'''Anneal in Furnace (C1):''' ANN1000, 30 min in N<sub>2</sub>, strip of oxide in a 25 min BHF etch. | |||
'''Wet oxidation in Furnace (C1):''' WET1050, 30 min, no further anneal | |||
'''Anneal in Furnace (C1):''' ANN950, 60 min in N<sub>2</sub> | |||
The wafers were then analyzed by SIMS and the results are shown in the figure below: | |||
[[image:PECVD_Boron_doping_profiles.jpg|627x424px|left|thumb|Boron concentration measured by SIMS. Results from Trine Holm Christensen, Space, Feb. 2015.]] | |||
<br clear="all" /> | |||
Measured peak concentrations and sheet resistances: | |||
<br> | |||
{| border="1" cellspacing="0" cellpadding="7" with="50" style="text-align:center;" | |||
|- | |||
|Wafer | |||
|Peak Concentration | |||
[atoms/cm<sup>3</sup>] | |||
|Sheet Resistance | |||
[Ω/sq] | |||
|- | |||
|BSG120 | |||
|1.75*10<sup>19</sup> | |||
|56.4 | |||
|- | |||
|BSG130 | |||
|2.44*10<sup>19</sup> | |||
|36.2 | |||
|- | |||
|BSG140 | |||
|2.36*10<sup>19</sup> | |||
|40.3 | |||
|- | |||
|} | |||
<br clear="all" /> | |||