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Specific Process Knowledge/Thin film deposition/Deposition of Vanadium Silicide/V3Si RF-DC Co-Sputtering in Cluster Lesker PC3: Difference between revisions

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This page documents an <b>early</b>, <b>non-systematic attempt</b> to deposit vanadium silicide by simultaneous RF sputtering of a 4-inch Si target and DC sputtering of a 3-inch V target in the <i>Cluster Lesker PC3</i> chamber. Two otherwise nominally identical depositions were compared: one without RF substrate bias and one with 30 W RF substrate bias.
This page documents an <b>early</b>, <b>non-systematic attempt</b> to deposit vanadium silicide by simultaneous RF sputtering of a 4-inch Si target and DC sputtering of a 3-inch V target in the <i>Cluster Lesker PC3</i> chamber. Two otherwise nominally identical depositions were compared: one without RF substrate bias and one with 30 W RF substrate bias.


We achieved the expected results for the V<sub>3</sub>Si process in PC1 and describe them here.
We achieved the expected results for the V<sub>3</sub>Si process in PC1 and describe them [[Specific Process Knowledge/Thin film deposition/Deposition of Vanadium Silicide/V3Si RF-DC Co-Sputtering in Cluster Lesker PC1|in dedicated page]].


The experiment gave a striking result. In the measured 30–80&deg; GiXRD range, the unbiased sample showed only reflections assigned to cubic A15 V<sub>3</sub>Si, whereas the sample deposited with 30 W RF substrate bias showed only reflections assigned to hexagonal C40 VSi<sub>2</sub>. The two samples also had very different surface morphologies and sheet resistances.
The experiment gave a striking result. In the measured 30–80&deg; GiXRD range, the unbiased sample showed only reflections assigned to cubic A15 V<sub>3</sub>Si, whereas the sample deposited with 30 W RF substrate bias showed only reflections assigned to hexagonal C40 VSi<sub>2</sub>. The two samples also had very different surface morphologies and sheet resistances.
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! XRR density
! XRR density
! XRR roughness
! XRR roughness
! Sheet resistance
 
! Calculated resistivity
|-
|-
| No substrate bias
| No substrate bias
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| 4.741 g/cm<sup>3</sup>
| 4.741 g/cm<sup>3</sup>
| 7.873 nm
| 7.873 nm
| 29.34 &Omega;/sq
 
| 276 &micro;&Omega;&middot;cm
|-
|-
| 30 W RF substrate bias (69 V DC bias)
| 30 W RF substrate bias (69 V DC bias)
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| Not obtained
| Not obtained
| Not obtained
| Not obtained
| 6.64 &Omega;/sq
| Not calculated because thickness is unknown
|}
|}