Specific Process Knowledge/Thin film deposition/ALD2 (PEALD)/AlN deposition using ALD2

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General Information

The AlN process should never run above 350 °C due to the decomposition of the trimethylaluminium. As already mentioned in the general ALD2 (PEALD) page oxides and nitrides cannot be deposited at the same time. Since the aluminium nitride requires the plasma source we only run all nitride processes without the thermal lid. Hence the chamber volume is bigger than with the thermal lid which causes that the substrate temperature is around 50 °C lower than the setpoint.

Result from acceptance test

Deposition of AlN using TMA and NH3 plasma

Recipe name: AlN NH3 plasma

Temperature window: 250 °C - 350 °C

The deposition rate is measure to be 0.137 nm/cycle for 350 °C with growth delay of 144 cycles.

TMA NH3
Nitrogen flow 100 sccm 150 sccm
Pulse time 0.1 s 5 s
Purge time 8 s 30 s


Plasma source settings
RF power (W) Ar carrier flow (sccm) Plasma gas flow (sccm) t1 stabilization (s) t2 RF Power on (s)
3000 150 100 1 3.4


Note! Remember to obey the relation: [Pulse time - (t1+t2)] > 0.5 s


Spectroscopic ellipsometry

Refractive index and permittivity

Thickness distribution and uniformity

X-ray photoelectron spectroscopy

Stoichiometry

Presence of Oxygen and Carbon