Specific Process Knowledge/Etch/Etching of Silicon Oxide

From LabAdviser

Silicon oxide can be etched using either wet chemistry or dry etch equipment. Wet chemistry is mainly used to remove all the oxide on the surface (backside and front side) of a wafer or for isotrotropic etching. Dry etching etches anisotropic. It etches one side of the wafer at a time and can be used to etch structures with several masking materials.

Etch of silicon oxide can be done by either wet etch or dry etch. The standard setups for this here at DANCHIP are:

Wet etches:

Dry etches:

Comparison of wet Silicon Oxide etch and dry etches (RIE and AOE) etch for etching of Silicon Oxide

Wet Silicon Oxide etch (BHF, SIO Etch (wetting agent), 5%HF) RIE AOE
General description
  • Isotropic etch
  • Anisotropic etch: vertical sidewalls
  • Anisotropic etch: vertical sidewalls, especially good for deep etch and high aspect ratio etch
Possible masking materials
  • Photoresist
  • Silicon nitride
  • Photoresist
  • (Poly)Silicon
  • Aluminium
  • Other metals that covers less the 5% of the wafer area (ONLY RIE2!)
  • Photoresist
  • (Poly)Silicon
  • Aluminium
  • Chromium (ONLY if the other masking materials can not be used!)
Etch rate
  • ~75 nm/min (Thermal oxide) in BHF
  • ~90 nm/min (Thermal oxide) in SIO Etch
  • ~25 nm/min (Thermal oxide) in 5%HF
  • Typically 40-120 nm/min can be increased or decreased by using other recipe parameters.
  • Typically 200-600 nm/min can be increased or decreased by using other recipe parameters.
Batch size
  • 1-25 wafers at a time
  • 1 wafer at a time
  • 1 wafer at a time
Size of substrate
  • 4" wafers
  • 4" wafers or smaller pieces
  • 6" or 4" depending on the setup (smaller pieces if you have a carrier wafer)
Allowed materials
  • Silicon
  • Silicon Oxide
  • Silicon Nitride
  • Silicon Oxynitride
  • Photoresist
  • Blue film
  • Gold (Au) and Nickel (Ni) (but only in BHF2 (KOH)!)
  • Silicon
  • Silicon Oxide
  • Silicon Nitride
  • Silicon Oxynitride
  • Photoresist
  • E-beam resist
  • Aluminium
  • Other metals that covers less the 5% of the wafer area (ONLY RIE2!)
  • Silicon
  • Silicon Oxide
  • Silicon Nitride
  • Silicon Oxynitride
  • Photoresist
  • E-beam resist
  • Aluminium
  • Chromium (ONLY as masking material if the other masking materials can not be used!)


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Comparing silicon oxide etch methods at Danchip

There are a broad varity of silicon oxide etch methods at Danchip. The methodes are compared here to make it easier for you to compare and choose the one that suits your needs.


Compare the methodes for Silicon Nitride etching

Wet Silicon Nitride Etch BHF RIE (Reactive Ion Etch) AOE (Advanced Oxide Etch) ASE (Advanced Silicon Etch) ICP Metal Etch IBE/IBSD Ionfab 300
Generel description
  • Isotropic etch
  • Well suited for removing all nitride on a wafer surface (nitride strip) without a mask. High selectivity Si3N4/Si (>100) and Si3N4/SiO2 (>20) @ 180 C.
  • Isotropic etch
  • Well suited for removing all PECVD nitride on a wafer surface (nitride strip) without a mask. Etches LPCVD nitride very slowly
  • Anisotropic etch: vertical sidewalls
  • AOE
  • ASE
  • This is dedicated to metal etch.
  • Primarily for pure physical etch by sputtering with Ar-ions
Possible masking materials
  • Silicon Oxide
  • PolySilicon
  • Photoresist
  • PolySilicon
  • Blue film
  • Photoresist
  • E-beam resist
  • Silicon Oxide
  • Silicon Nitride
  • Aluminium
  • Metals if they cover less than 5% of the wafer area (ONLY RIE2!)

AOE

  • Photoresist and zep resist
  • Silicon Oxide
  • Silicon Nitride
  • Aluminium oxide

ASE

  • Photoresist
  • Silicon Oxide
  • Silicon Nitride
  • Aluminium

ICP Metal

  • Photo-, DUV- and e-beamresist
  • Silicon Oxide
  • Silicon Nitride
  • Aluminium
  • Cr
  • Ti
  • Any material that is accepted in the machine
Etch rate range
  • Si3N4 @ 180 oC: ~84 Å/min
  • Si3N4 @ 160 oC: ~60 Å/min
  • PECVD nitride: ~400-1000 Å/min
  • Typically 40-50 nm/min can be increased or decreased by using other recipe parameters.

AOE

ASE

ICP metal

  • Process dependant. Has not been tested yet.
Substrate size
  • #1-25 100 mm wafers
  • #1-25 100mm wafers in our 100mm bath
  • As many small samples as can be fitted on the 100mm carrier.
  • #1 100mm wafer (or smaller with carrier)
  • #1 150mm wafer (only when the system is set up for 150mm)
  • As many small samples as can be fitted on a 100mm wafer
  • #1 50 mm wafer fitted on a 100mm wafer
  • #1 100 mm wafer
  • #1 150 mm wafers (only when the system is set up to 150mm)
  • As many small samples as can be fitted on a 100mm wafer
  • #1 50 mm wafer fitted on a 100mm wafer
  • #1 100 mm wafer
  • #1 150 mm wafers (only when the system is set up to 150mm)
  • As many small samples as can be fitted on a 150mm wafer
  • #5 50 mm wafer fitted on a 150mm wafer
  • #1 100 mm wafer on a 150mm wafer
  • #1 150 mm wafers (The system is normally set up to 150mm)
  • As many samples as can be securely fitted on a up to 200mm wafer
  • #1 50 mm wafer with special carrier
  • #1 100 mm wafer with special carrier
  • #1 150 mm wafers with special carrier
  • #1 200 mm wafer
Allowed materials
  • Silicon
  • Silicon Oxide
  • Silicon Nitride
  • Silicon Oxynitride
  • Silicon
  • Silicon Oxide
  • Silicon Nitride
  • Silicon Oxynitride
  • Photoresist
  • Blue film
  • Silicon
  • Silicon Oxide
  • Silicon Nitride
  • Silicon Oxynitride
  • Photoresist
  • E-beam resist
  • Other metals if they cover less than 5% of the wafer area (ONLY RIE2!)
  • Quartz/fused silica
  • Silicon
  • Silicon Oxide
  • Silicon Nitride
  • Silicon Oxynitride
  • Photoresist
  • zep resist
  • Aluminium
  • Chromium (try to avoid it)
  • Quartz/fused silica
  • Silicon
  • Silicon Oxide
  • Silicon Nitride
  • Silicon Oxynitride
  • Photoresist
  • E-beam resist
  • Aluminium
  • Quartz/fused silica
  • Silicon
  • Photoresist/e-beam resist
  • PolySilicon
  • Silicon oxide
  • Silicon (oxy)nitride
  • Aluminium
  • Titanium
  • Chromium
  • Quartz/fused silica
  • Silicon
  • Silicon oxides
  • Silicon (oxy)nitrides
  • Metals from the +list
  • Metals from the -list
  • Alloys from the above list
  • Stainless steel
  • Glass
  • III-V materials
  • Resists
  • Polymers
  • Capton tape