LabAdviser/Technology Research/Technology for CZTS-Silicon Tandem Solar Cells

From LabAdviser

Fabrication of surfaces for the promotion of bacterial biofilms

Project description

Thanks to the drastic cost reductions over the last few decades, photovoltaic (PV) technology, which directly converts the sunlight into usable electricity, has become one of the most prominent sources of renewable energy. As the balance of system costs now dominates the cost of PV systems, the demand to increase the efficiency of PV modules has surged. However, the efficiency improvements in most mature PV technologies, in particular the Si solar cells as the most dominant technology, are only marginal as they are approaching their fundamental limits. In this regard, multijunction or tandem solar cells have emerged as the most compelling solution to surpass the so-called Shockley–Queisser limit and realize efficiency beyond 30%. In a tandem solar cell, two (or more) sub-cells with complementary bandgaps are combined in a vertical stack to harvest the solar spectrum more efficiently with lower thermalization (heat) losses. Silicon-based tandem solar cells, which couple the conventional silicon technology with a high bandgap material, are practically and economically the most favorable configuration since the enhanced efficiency can be realized by adding a few additional steps to the existing well-developed technology. Thin-film chalcogenides are enticing candidates for the top cell material as they have exhibited cost, performance, and stability comparable to the silicon technology. Despite their promise, the growth of such materials, which are usually produced at high temperatures (500-600 oC) under harsh reactive atmospheres (e.g., S or Se), on silicon is exceptionally challenging. During the high-temperature process, harmful metallic elements (e.g., Cu), which chalcogenides contain in abundance, can diffuse to the silicon bottom cell and severely damage its photovoltaic performance.

In this thesis, we chose CuZnSnS4, a quaternary compound semiconductor with a bandgap of 1.5 eV, as a promising non-toxic, earth-abundant, and cheap representative candidate from the chalcogenide family, and systematically studied the integration challenges with silicon. For this purpose, we developed and optimized a thermally resilient silicon cell structure with polysilicon carrier selective contacts, and used an ultrathin (< 10 nm) titanium nitride-based diffusion barrier at the interface of the two cells (called the “barrier layer”) to protect the silicon cell against contamination. Throughout the thesis, we showed that the performance of the CZTS-Si tandem devices heavily relies on the electrical, optical, and protection behavior of the barrier layer. By proper engineering of the TiN and polysilicon interfacial layers, we managed to keep the silicon cell almost intact during the full fabrication of CZTS, and demonstrated a world-record efficiency of 4.1% for this type structure. Our findings implicate that the growth of new materials, with a wide range of thermal budgets and compositions, is technically feasible on silicon. Moreover, we believe that our proposed tandem structure may provide new insights for the Si community in terms of device architecture engineering for future silicon-based tandem cells.

Publications

Name of publication 1 made in this project

Reference and link to the publication

Name of publication2 made in this project

Reference and link to the publication

Name of publication3 made in this project

Reference and link to the publication


Fabrication: Process flows

This fabrication process flow is used for the fabrication of the silicon bottom cell.

Process flow (word format):

Retrieved from "https://labadviser.nanolab.dtu.dk//index.php?title=LabAdviser/Technology_Research/Technology_for_CZTS-Silicon_Tandem_Solar_Cells&oldid=37747"