Specific Process Knowledge/Etch/Wet Polysilicon Etch: Difference between revisions

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[[Image:Wet_PolySi_etch.jpg|300x300px|thumb|Wet PolySilicon Etch (in the middle): positioned in cleanroom 4]]
[[Image:Wet_PolySi_etch.jpg|300x300px|thumb|Wet PolySilicon Etch (in the middle): positioned in cleanroom 4]]


The wet Poly Etch is an isotropic silicon etch. This holds for both a poly-silicon thin-film as well as single-crystalline material such as a Si(100) surface. The Poly-Silicon Etch process is placed in a dedicated PP-tank in cleanroom 4.
The wet Poly Etch is an isotropic silicon etch. This holds for both a poly-silicon thin-film as well as single-crystalline material such as a Si(100) surface. The Poly Etch process is placed in a dedicated PP-tank in cleanroom 4.


Etching of silicon nitride - stoichiometric and si-rich - is done in a dedicated laminar flow bench with an integrated quartz tank (Tiger Tank - TT-4). The quartz tank can take up to one 6" wafer carrier. The flow bench is placed in cleanroom 4. The process is mainly used to strip silicon nitride (maskless), but can also be used for masked etching of silicon nitride using some kind of silicon oxide as etch mask. However, the wet silicon nitride etch is isotropic meaning that the under-etching (etch-bias) at least amounts to the thickness of the silicon nitride layer.
Etching of silicon nitride - stoichiometric and si-rich - is done in a dedicated laminar flow bench with an integrated quartz tank (Tiger Tank - TT-4). The quartz tank can take up to one 6" wafer carrier. The flow bench is placed in cleanroom 4. The process is mainly used to strip silicon nitride (maskless), but can also be used for masked etching of silicon nitride using some kind of silicon oxide as etch mask. However, the wet silicon nitride etch is isotropic meaning that the under-etching (etch-bias) at least amounts to the thickness of the silicon nitride layer.

Revision as of 12:14, 30 January 2008

Wet Poly Etch

Wet PolySilicon Etch (in the middle): positioned in cleanroom 4

The wet Poly Etch is an isotropic silicon etch. This holds for both a poly-silicon thin-film as well as single-crystalline material such as a Si(100) surface. The Poly Etch process is placed in a dedicated PP-tank in cleanroom 4.

Etching of silicon nitride - stoichiometric and si-rich - is done in a dedicated laminar flow bench with an integrated quartz tank (Tiger Tank - TT-4). The quartz tank can take up to one 6" wafer carrier. The flow bench is placed in cleanroom 4. The process is mainly used to strip silicon nitride (maskless), but can also be used for masked etching of silicon nitride using some kind of silicon oxide as etch mask. However, the wet silicon nitride etch is isotropic meaning that the under-etching (etch-bias) at least amounts to the thickness of the silicon nitride layer.

The etch solution is initially 85 wt% H3PO4 which is heated up to the boiling temperature - ca. 157 oC. Water is allowed to boil off thus raising the concentration and the boiling temperature of the solution until a boiling temperature of 180 oC is reached. Thereafter, the wafers are submerged into the bath and the water-cooled lid is closed to maintain the concentration and the boiling temperature. In some cases a lower boiling temperature is chosen - typically 160 oC - which lowers the etch rate and improves the selectivity RSi3N4 / RSiO2.


NB: Great care has to be taken in this process due to risk of "shock-boiling"


Nitride etch - key facts

Nitride etch @ 180 oC Nitride etch @ 160 oC
General description

Etch/strip of silicon nitride

Etch/strip of silicon nitride

Chemical solution H3PO4 (85 wt%) H3PO4 (85 wt%)
Process temperature 180 oC 160 oC
Possible masking materials:
  • Thermal oxide (converted si-rich surface)
  • LPCVD-oxide (TEOS)
  • PECVD-oxide
  • Thermal oxide (converted si-rich surface)
  • LPCVD-oxide (TEOS)
  • PECVD-oxide
Etch rate
  • ~85 Å/min (stoichiometric Si3N4)
  • ~60 Å/min (si-rich Si3N4)
  • ~30 Å/min (annealed si-rich Si3N4)
  • ~4 Å/min (Thermal oxide)
  • ~26 Å/min (si-rich Si3N4)
  • ~? Å/min (Thermal oxide)
Batch size

1-25 wafers at a time

1-25 wafer at a time

Size of substrate

2-6" wafers

2-6" wafers