Specific Process Knowledge/Lithography/UVExposure Dose: Difference between revisions

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#REDIRECT [[Specific Process Knowledge/Lithography/Resist#Exposure_dose]]
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=Exposure dose=
=Exposure dose=
[[Image:AZ spectral sensitivity.gif|400x400px|thumb|Spectral sensitivity of AZ resists represented as optical absorption. From http://www.microchemicals.com/]]
[[Image:AZ photoresists spectral sensitivity - remake v1.png|400x400px|thumb|Spectral sensitivity of AZ resists represented as optical absorption.]]


During exposure of the resist, the photoinitiator, or photo-active component, reacts with the exposure light, and starts the reaction that makes the resist develop in the developer. In a positive resist, it makes the resist become soluble in the developer. In a negative resist, usually assisted by thermal energy in the post-exposure bake, it makes the resist insoluble in the developer. The amount of light required to fully develop the resist in the development process, is the exposure dose.
During exposure of the resist, the photoinitiator, or photo-active component, reacts with the exposure light, and starts the reaction that makes the resist develop in the developer. In a positive resist, it makes the resist become soluble in the developer. In a negative resist, usually assisted by thermal energy in the post-exposure bake, it makes the resist insoluble in the developer. The amount of light required to fully develop the resist in the development process, is the exposure dose.
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It is important to keep in mind that this exposure time is valid only for a specific combination of exposure source and optical sensor, as well as for a specific development process.
It is important to keep in mind that this exposure time is valid only for a specific combination of exposure source and optical sensor, as well as for a specific development process.


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==Comparison: Relative exposure dose==
==Comparison: Relative exposure dose==
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<sup>1)</sup> Due to a difference in the sensitivity of the power meter used in calibration.
<sup>1)</sup> Due to a difference in the sensitivity of the power meter used in calibration.
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|-
|-
|-style="background:WhiteSmoke; color:black"
|-style="background:WhiteSmoke; color:black"
!rowspan="2"|AZ 5214E
!rowspan="2"|AZ 5214E<br><span style="color:red">Old German version</span>
|Long ago
|Long ago
|1.5 µm
|1.5 µm
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|-
|-
|-style="background:LightGrey; color:black"
|-style="background:LightGrey; color:black"
!rowspan="2"|AZ 5214E Image Reversal
!rowspan="2"|AZ 5214E Image Reversal<br><span style="color:red">Old German version</span>
|Long ago
|Long ago
|1.5 µm
|1.5 µm
|22? mJ/cm<sup>2</sup>
|22 mJ/cm<sup>2</sup>
|Single puddle, 60 s
|Single puddle, 60 s
|rowspan="2"|Image reversal process.<br>Reversal bake: 120s at 110°C.<br>Flood exposure: 200 mJ/cm<sup>2</sup>
|rowspan="2"|Image reversal process.<br>Reversal bake: 120s at 110°C.<br>Flood exposure: 200 mJ/cm<sup>2</sup>
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|-
|-
|-style="background:WhiteSmoke; color:black"
|-style="background:WhiteSmoke; color:black"
!AZ 4562
!rowspan="3"|AZ MiR 701<br><span style="color:red">Old PFOA containing version</span>
|Long ago
|10 µm
|520-?? mJ/cm<sup>2</sup>
|Multiple puddle, 4 x 60 s
|Multiple exposure with 10 s pauses is recommended.<br>Process not yet established.
|-
 
|-
|-style="background:LightGrey; color:black"
!rowspan="3"|AZ MiR 701
|Long ago
|Long ago
|1.5 µm
|1.5 µm
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|Single puddle, 60 s
|Single puddle, 60 s
|rowspan="2"|PEB: 60 s at 110°C
|rowspan="2"|PEB: 60 s at 110°C
|-style="background:LightGrey; color:black"
|-style="background:WhiteSmoke; color:black"
|Long ago
|Long ago
|2 µm
|2 µm
|~200 mJ/cm<sup>2</sup>
|~200 mJ/cm<sup>2</sup>
|Single puddle, 60 s
|Single puddle, 60 s
|-style="background:LightGrey; color:black"
|-style="background:WhiteSmoke; color:black"
|Long ago
|Long ago
|4 µm
|4 µm
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|-
|-
|-style="background:WhiteSmoke; color:black"
|-style="background:LightGrey; color:black"
!AZ nLOF 2020
!AZ nLOF 2020
|Long ago
|Long ago
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|PEB: 60 s at 110°C<br>Use 60 s development for lift-off
|PEB: 60 s at 110°C<br>Use 60 s development for lift-off
|-
|-
|-
|-style="background:WhiteSmoke; color:black"
!AZ 5214E<br><span style="color:green">New Japanese version</span>
|2023-01-11<br>jehem
|1.5 µm
|70 mJ/cm<sup>2</sup>
|Single puddle, 60 s
|
|-
|-
|-style="background:LightGrey; color:black"
!AZ 5214E Image Reversal<br><span style="color:green">New Japanese version</span>
|2023-01-11<br>jehem
|2.2 µm
|22 mJ/cm<sup>2</sup>
|Single puddle, 60 s
|Image reversal process.<br>Reversal bake: 60s at 110°C.<br>Flood exposure: 500 mJ/cm<sup>2</sup>
|-
|-
|-style="background:WhiteSmoke; color:black"
!AZ 4562<br><span style="color:green">New Japanese version</span>
|2021-12-08<br>jehem
|10 µm
|550 mJ/cm<sup>2</sup>
|Multiple puddles, 5 x 60 s
|Priming: HMDS<BR>Rehydration after SB: 1 hour (may not be necessary)<br>Exposure: Multiple exposures with pauses, 5 x (10 s exposure + 10 s pause)<br>Degassing after exposure: 1 hour (may not be necessary)
|-
|-
|-style="background:LightGrey; color:black"
!AZ MiR 701<br><span style="color:green">New PFOA free version</span>
|2021-06-23<br>elkh
|1.5 µm
|~150 mJ/cm<sup>2</sup>
|Single puddle, 60 s
|PEB: 60 s at 110°C
|-
|}
|}
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'''AZ 5214E image reversal'''
'''AZ 5214E image reversal'''
*1.5 µm resist on boron glass: around 49 mJ/cm<sup>2</sup> (supplied March 2013 by Morten Bo Lindholm Mikkelsen, DTU Nanotech).
*1.5 µm resist on boron glass: around 49 mJ/cm<sup>2</sup> (supplied March 2013 by Morten Bo Lindholm Mikkelsen, DTU Nanotech).
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Latest revision as of 10:47, 23 October 2023